27890-58-0Relevant academic research and scientific papers
Neutral lewis base adducts of silicon tetraazide
Portius, Peter,Filippou, Alexander C.,Schnakenburg, Gregor,Davis, Martin,Wehrstedt, Klaus-Dieter
, p. 8013 - 8016 (2010)
Highly energetic and still stable: The first base adducts of silicon tetraazide, Si(N3)4(L2) (L2= bipyridine, 1,10-phenanthroline), were prepared and fully characterized (picture: the ball and stick model of the
Reactions of silicon atoms with nitrogen: A combined matrix spectroscopic and density functional theory study
Maier, Günther
, p. 4775 - 4783 (2000)
Cocondensation of thermally generated silicon atoms with an excess of nitrogen at 12 K offers an access to new binary silicon-nitrogen compounds. In addition to the well-known linear dinitrogensilicon, SiNN (1-T), six new species containing one (2, 3) or two silicon atoms (4-7) have been isolated and identified by matrix spectroscopy and their mutual photochemical transformations. The structural elucidation of the new compounds 2-7 is based on isotopic labeling experiments and density functional theory calculations.
SILICON POLYAZIDES AND A METHOD FOR THEIR PRODUCTION
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Page 7, (2008/06/13)
The invention relates to silicon polyazides of general formula (I) (K+)n[L2-nSi(N3) 4+n] (n)-, in which n has the value 0 or 2, L represents N-heterocyclic compounds, K represents alkali me
