27892-76-8

Upstream product

• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 1402671-84-4 C₁₈H₂₇N₄O₃S⁽¹⁺⁾*CF₃O₃S^(1-) 
• 717-14-6 4-methoxyacetophenone semicarbazone 

Downstream Products

• 63418-50-8 4-[(4-methoxy-phenyl)-selenoacetyl]-morpholine 
• 93515-74-3 N-[5-(4-Methoxy-phenyl)-[1,3]thiaselenol-(2E)-ylidene]-4-methyl-benzamide 
• 57444-37-8 Potassium; (4-methoxy-phenyl)-ethyneselenolate 
• 74277-57-9 [5-(4-Methoxy-phenyl)-[1,3]thiaselenol-(2Z)-ylidene]-carbamic acid ethyl ester 
• 93515-73-2 N-[5-(4-Methoxy-phenyl)-[1,3]thiaselenol-(2E)-ylidene]-benzamide 
• 127901-82-0 [4-(4-Methoxy-phenyl)-[1,3]diselenol-(2Z)-ylidene]-phenyl-amine 
• 102104-54-1 2-(4-Methoxy-phenylethynylselanylmethyl)-oxirane 
• 102104-58-5 1,3-Bis-(4-methoxy-phenylethynylselanyl)-propan-2-ol 
• 107406-47-3 1-Phenyl-2-(2-ethynylselenomercapto)ethanol 
• 107378-44-9 2-(4-Methoxy-phenylethynylselanyl)-1-phenyl-ethanone 
• 107378-45-0 1-(4-Methoxy-phenylethynylselanyl)-propan-2-one 
• 107378-46-1 1-(2-ethynylselenomercapto)-2-propanol 
• 91585-32-9 ((4-methoxyphenyl)ethynyl)(phenyl)selane 
• 81888-38-2 1-Methoxy-4-methylselanylethynyl-benzene 

Relevant academic research and scientific papers

Preparation of 2-Arylethynylselanylacetonitriles from 4-Aryl-1,2,3-selenadiazoles

Base decomposition of 4-(substituted phenyl)-1,2,3-selenadiazoles at room temperature resulted in 2-(substituted phenyl)-ethynylselenolate anions, which were immediately reacted with bromoacetonitrile to give a series of 2-(substituted phenyl)ethynylselan

Ionic liquid as soluble support for synthesis of 1,2,3-thiadiazoles and 1,2,3-selenadiazoles

A convenient synthesis of 1,2,3-thiadiazoles and 1,2,3-selenadiazoles was achieved using an ionic liquid as a novel soluble support. Ionic liquid-supported sulfonyl hydrazine was synthesized and reacted with a number of ketones to afford the corresponding ionic liquid-supported hydrazones that were converted to 1,2,3-thiadiazoles in the presence of thionyl chloride. The reaction of ionic liquid-supported hydrazones with selenium dioxide in acetonitrile afforded 1,2,3-selenadiazoles. The advantages of this methodology were the ease of workup, simple reaction conditions, and high purity.