27934-74-3

Usage

Physical state

Colorless liquid

Molecular weight

118.59 g/mol

Uses

a. Production of chemicals and materials
b. Pharmaceutical industry
c. Agrochemicals
d. Polymers
e. Intermediate in organic synthesis
f. Creation of complex organic molecules
g. Starting material for synthesis of other compounds

(Z)-configuration

Indicates that the two chlorine atoms are on the same side of the double bond

Safety precautions

a. Flammability
b. Harmful if inhaled
c. Harmful if ingested
d. Harmful if in contact with skin

Upstream product

• 80411-43-4 chloroallyllithium 
• 106-95-6 allyl bromide 
• 107-05-1 3-chloroprop-1-ene 

Relevant academic research and scientific papers

Reactions of α-haloallyllithium derivatives with carbon, silicon, tin or boron halides and carbonyl compounds

A series of allylic halides have been converted into their α-carbanions with strong lithium bases, using different techniques.These have been compared in their reaction with various electrophiles leading to functionally substituted allyl derivatives.The influence of the counterion on the regio- and stereoselectivity has been investigated. allylic halides / α-halocarbanions / allylsilanes / allyltin derivatives / α-chlorohydrins / vinylepoxides / diastereoselectivity

ETUDE DE L'ALKYLATION D'ORGANOLITHIENS ALLYLIQUES MONOCHLORES: SYNTHESE EN UNE ETAPE DE CHLORURES ALLYLIQUES SECONDAIRES OU TERTIAIRES ET/OU DE CHLORURES VINYLIQUES DE CONFIGURATION Z

Chloroallyllithium and gem-chloro(methyl)allyllithium readily react with various alkylating reagents to produce, in a "one-pot" reaction, secundary or tertiary allylic chlorides and/or vinylic chlorides of Z configuration.