27948-10-3

Basic information

• Product Name: hexyl cyclohexanecarboxylate
• Synonyms: hexyl cyclohexanecarboxylate;Cyclohexanecarboxylic acid hexyl ester
• CAS NO: 27948-10-3
• Molecular Formula: C₁₃H₂₄O₂
• Molecular Weight: 212.32846
• EINECS: 248-744-7
• Mol File: 27948-10-3.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 265.1 °C at 760 mmHg
• Flash Point: 104.6 °C
• Appearance: /
• Density: 0.937 g/cm³
• Vapor Pressure: 0.00935mmHg at 25°C
• Refractive Index: 1.457
• CAS DataBase Reference: hexyl cyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: hexyl cyclohexanecarboxylate(27948-10-3)
• EPA Substance Registry System: hexyl cyclohexanecarboxylate(27948-10-3)

Safety Data

• Hazardous Substances Data: 27948-10-3(Hazardous Substances Data)

Usage

General Description

Hexyl cyclohexanecarboxylate, also known as cyclomene, is a chemical compound commonly used in the cosmetic and fragrance industries. It is a clear, colorless liquid with a sweet, fruity odor. Hexyl cyclohexanecarboxylate is often used as a fragrance ingredient in perfumes, colognes, and other scented products due to its pleasant aroma. It can also be found in personal care products such as lotions, creams, and soaps. This chemical compound is considered safe for use in cosmetics and personal care products when used in accordance with good manufacturing practices.

InChI:InChI=1/C13H24O2/c1-2-3-4-8-11-15-13(14)12-9-6-5-7-10-12/h12H,2-11H2,1H3

Upstream product

• 111-27-3 hexan-1-ol 
• 98-89-5 Cyclohexanecarboxylic acid 
• 110-82-7 cyclohexane 
• 201230-82-2 carbon monoxide 
• 6789-88-4 hexyl benzoate 
• 35665-26-0 N-benzylcyclohexanecarboxamide 
• 2719-27-9 cyclohexanylcarbonyl chloride 

Relevant articles and documents

Cobalt-Nanoparticles Catalyzed Efficient and Selective Hydrogenation of Aromatic Hydrocarbons

The development of inexpensive and practical catalysts for arene hydrogenations is key for future valorizations of this general feedstock. Here, we report the development of cobalt nanoparticles supported on silica as selective and general catalysts for such reactions. The specific nanoparticles were prepared by assembling cobalt-pyromellitic acid-piperazine coordination polymer on commercial silica and subsequent pyrolysis. Applying the optimal nanocatalyst, industrial bulk, substituted, and functionalized arenes as well as polycyclic aromatic hydrocarbons are selectively hydrogenated to obtain cyclohexane-based compounds under industrially viable and scalable conditions. The applicability of this hydrogenation methodology is presented for the storage of H2 in liquid organic hydrogen carriers.

Cesium Carbonate Catalyzed Esterification of N-Benzyl- N-Boc-amides under Ambient Conditions

We report a general activated amide to ester transformation catalyzed by Cs2CO3. Using this approach, esterification proceeds under relatively mild conditions and without the need for a transition metal catalyst. This method exhibits broad substrate scope and represents a practical alternative to existing esterification strategies. The synthetic utility of this protocol is demonstrated via the facile synthesis of crown ether derivatives and the late-stage modification of a representative natural product and several sugars in reasonable yields.

Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes

A metal-free radical oxidative carbonylation of alkanes is demonstrated, yielding esters and imides by means of di-tert-butylperoxide as an oxidant. Various alkanes, alcohols and amides were compatible in this system generating the desired carbonyl products in up to 86% yields. We proposed a plausible radical cross-coupling process based on the preliminary mechanistic studies.