27958-95-8

Basic information

• Product Name: N,N-diethyl-3-(methoxyl)benzenemethanamine
• Synonyms: N,N-diethyl-3-(methoxyl)benzenemethanamine
• CAS NO: 27958-95-8
• Molecular Weight: 193.289
• Mol File: 27958-95-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: N,N-diethyl-3-(methoxyl)benzenemethanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diethyl-3-(methoxyl)benzenemethanamine(27958-95-8)
• EPA Substance Registry System: N,N-diethyl-3-(methoxyl)benzenemethanamine(27958-95-8)

Safety Data

• Hazardous Substances Data: 27958-95-8(Hazardous Substances Data)

Upstream product

• 109-89-7 diethylamine 
• 874-98-6 1-bromomethyl-3-methoxybenzene 
• 591-31-1 3-methoxy-benzaldehyde 
• 78358-11-9 methanesulfonic acid 3-methoxy-benzyl ester 
• 617-84-5 N-formyldiethylamine 
• 824-98-6 m-methoxybenzyl chloride 

Downstream Products

• 27958-96-9 1-(diethylaminomethyl)-3-hydroxybenzene 
• 1073268-79-7 C₂₄H₃₆N₂O₂Se₂ 
• 1073269-01-8 C₁₂H₁₉NO₂Se 
• 1073268-87-7 C₁₂H₁₉NOSe 

Relevant articles and documents

Consecutive β,β′-Selective C(sp3)?H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C6F5)3

Tris(pentafluorophenyl)borane has been found to catalyze the two-fold C(sp3)?H silylation of various trialkylamine derivatives with dihydrosilanes, furnishing the corresponding 4-silapiperidines in decent yields. The multi-step reaction cascade involves amine-to-enamine dehydrogenation at two alkyl residues and two electrophilic silylation reactions of those enamines, one inter- and one intramolecular.

Fluorine-containing compound and synthesis method thereof

The embodiment of the invention discloses a fluorine-containing compound and a synthesis method thereof. The method comprises the steps of allowing a compound shown as formula (II) as shown in the specification and a compound shown as formula (III) as shown in the specification to react under the action of a fluorine reagent to generate: (1) the fluorine-containing compound shown as formula (I) as shown in the specification in the presence of water, and (2) the fluorine-containing compound shown as formula (IV) as shown in the specification in the absence of the water. The synthesis method of the fluorine-containing compound does not require a transition metal and is safer; the fluorine-containing compound is synthesized only by a one-step reaction; and the method is very simple and convenient.

Highly efficient amination in neat water of benzyl chlorides with dialkylformamides catalysed by N-heterocyclic carbene-palladium(II)-1- methylimidazole complex

Dialkylformamides are excellent N-sources in the amination of benzyl chlorides when catalysed by a NHC-Pd(II)-Im complex. In the presence of NaOH and the catalyst, variously substituted benzyl chlorides and five different dialkylformamides reacted smoothly to afford the corresponding N,N-dialkyl-benzylamines in good to almost quantitative yields in eco-friendly solvent water at 50 °C within 3 h.