27975-62-8Relevant academic research and scientific papers
Remarkable template effect of a Lewis acid receptor in the intramolecular radical cyclization: Control of reaction pathway as well as stereochemistry
Ooi, Takashi,Hokke, Yasutoshi,Tayama, Eiji,Maruoka, Keiji
, p. 135 - 144 (2001)
A remarkable template effect in the intramolecular radical cyclization process has been observed by the successful utilization of Lewis acid receptor, aluminum tris(2,6-diphenylphenoxide) (ATPH). The origin of this efficient template effect by ATPH would
Remarkable template effect of a Lewis acidic receptor in intramolecular radical cyclizations
Ooi,Hokke,Maruoka
, p. 1181 - 1183 (2007/10/03)
The bowl-shaped reaction environment created by the Lewis acid aluminum tris(2,6-diphenylphenoxide) has been utilized as an efficient template in intramolecular radical cyclizations. The pathway and the stereoselectivity of the radical cyclization can be
