280783-69-9Relevant academic research and scientific papers
Carbenium ion trapping using sulfonamides: an acid-catalysed synthesis of pyrrolidines by intramolecular hydroamination
Griffiths-Jones (née Haskins), Charlotte M.,Knight, David W.
experimental part, p. 4150 - 4166 (2010/07/05)
Cyclisations of homoallylic sulfonamides proceed smoothly via carbenium ion generation using trifluoromethanesulfonic (triflic) acid, the ease of cyclisation being directly related to the ion stability to give good to excellent yields of the corresponding pyrrolidines. Both toluene- and nitrophenyl-sulfonyl groups are suitable for all substrates tested whereas the corresponding carbamates are only useful in cases of tertiary and highly stabilised carbenium ions. Polyene-derived sulfonamides can also be cyclised to the corresponding polycyclic systems in remarkably high yields, in reactions reminiscent of related cascades encountered in terpene biosynthesis.
Bridged (β-alkoxyalkyl)CoIII(salen) complexes by intramolecular alkoxycobaltation of unactivated alkenes: New models for coenzyme B12
Blaauw, Rolf,Kingma, Irene E.,Laan, Jan H.,Van Der Baan, Juul L.,Balt, Sijbe,De Bolster, Martinus W. G.,Klumpp, Gerhard W.,Smeets, Wilberth J. J.,Spek, Anthony L.
, p. 1199 - 1210 (2007/10/03)
CoII(salen) derivatives (salen = {N,N′-ethylenebis[salicylideneaminato]}) whose ethanediyl moiety carries an alkenyl side-chain R [R = prop-2-en-1-yl (6a), 2-methylprop-2-en-1-yl (6b), but-2-en-1-yl (6c), but-3-en-1-yl (6d)] react with oxygen a
