28097-77-0Relevant academic research and scientific papers
Reaction of primary phosphines with elemental sulfur and alkali metal hydroxides (MOH, M = Na, K, Cs): A novel and facile three-component synthesis of trithiophosphonates
Artem'Ev, Alexander V.,Gusarova, Nina K.,Malysheva, Svetlana F.,Mamatyuk, Victor I.,Gatilov, Yurii V.,Trofimov, Boris A.
, p. 398 - 400 (2011)
Primary phosphines readily react with elemental sulfur and alkali metal hydroxides (MOH, M = Na, K, Cs) in the molar ratio 1:3:2 under mild conditions (70 °C, 0.5 h, ethanol) to afford alkali metal trithiophosphonates in good to high yields (72-90%).
Three-component reaction between elemental sulfur, primary phosphines, and amines: Straightforward synthesis of organylammonium trithiophosphonates
Artem'Ev, Alexander V.,Malysheva, Svetlana F.,Belogorlova, Nataliya A.,Gusarova, Nina K.
, p. 227 - 232 (2013)
Elemental sulfur reacts with primary phosphines and various amines in the 3:1:2 molar ratio under mild conditions (60°C, 10 min, ethanol) to afford hitherto unknown organylammonium trithiophosphonates in 84-91% yields.
CaII, YbII and SmII Bis(Amido) Complexes Coordinated by NHC Ligands: Efficient Catalysts for Highly Regio- and Chemoselective Consecutive Hydrophosphinations with PH3
Lapshin, Ivan V.,Basalov, Ivan V.,Lyssenko, Konstantin A.,Cherkasov, Anton V.,Trifonov, Alexander A.
, p. 459 - 463 (2019/01/04)
The first example of intermolecular hydrophosphination of styrene, 2-vinylpyridine and phenylacetylene with PH3 catalyzed by bis-(amido) complexes [(Me3Si)2N]2M(NHC)2 (M=Ca, Yb, Sm) coordinated by NHC
Reactions of Red Phosphorus with Electrophiles in Superbasic Systems. VIII. Reactions of Red Phosphorus and Phosphine with Arylalkenes
Arbuzova,Gusarova,Malysheva,Brandsma,Albanov,Trofimov
, p. 54 - 58 (2007/10/03)
With styrene and α-methylstyrene as examples red phosphorus and phosphine were shown to react with arylalkenes in a superbasic system (KOH/DMSO), yielding bis(2-phenylethyl)phosphine, bis(2-phenylpropyl)phosphine, bis(2-phenylethyl)phosphine oxide, bis(2-phenylpropyl)phosphine oxide, 2-phenylethylphosphinic and 2-phenylpropylphosphinic acids, and tris(2-phenylethyl)phosphine oxide. Conditions for preparation of secondary phosphines and phosphine oxides were found. Phosphine was generated by treating red phosphorus wuth aqueous potassium or sodium hydroxide.
