281-33-4

Usage

General Description

2,8,9-Trioxa-1-phosphadamantane is a chemical compound with the molecular formula C7H13O3P. It is a phosphorous-containing derivative of the organic compound adamantine, which is a rigid, cage-like structure. 2,8,9-Trioxa-1-phosphadamantane is commonly used as a ligand in coordination chemistry and as a building block in the synthesis of other organic and inorganic compounds. It has been studied for its potential applications in drug delivery systems and as a catalyst in organic reactions. The unique structural and chemical properties of 2,8,9-Trioxa-1-phosphadamantane make it a valuable tool in various chemical and biological research endeavors.

InChI:InChI=1/C6H9O3P/c1-4-2-6-3-5(1)8-10(7-4)9-6/h4-6H,1-3H2

Upstream product

• 2041-15-8 1,3,5-cyclohexanetriol 
• 50409-12-6 cis,cis-1,3,5-trihydroxycyclohexane 
• 108-73-6 3,5-dihydroxyphenol 

Downstream Products

• 875-12-7 α-Cyclohexantriol-(1a,3a,5a)-phosphat 
• 34442-16-5 C₈H₁₃O₅P 
• 75543-69-0 Phenyl-(2,8,9-trioxa-1λ⁵-phospha-tricyclo[3.3.1.1^3,7]dec-1-ylidene)-amine 
• 14882-45-2 {⁽²⁸⁾Ni(9-Trioxa-1-phospha-adamantan)4} 
• 15521-52-5 (CO)3NiPO₃C₆H₉ 
• 15679-87-5 (CO)2Ni(PO₃C₆H₉)2 
• 15189-06-7 {Ni(CO)(C₆H₉O₃P)3} 

Relevant academic research and scientific papers

ETUDE DE LA REACTIVITE DE QUELQUES PHOSPHOR(III)ADAMANTANES

A new phosphor(III)adamantan has been synthesized.The reactivity of that compound and of other phosphor(III)adamantans has been investigated.New phosphazens and new spirophosphorans have been obtained.The weak reactivity of these phosphor(III)adamantans can be explained in terms of hybridization of the phosphorus free electron pair.

Effects of Molecular Structure on basicity. Gas-Phase Proton Affinities of Cyclic Phosphites

The proton affinities of several monocyclic and bicyclic phosphite esters are determined by ion cyclotron resonance spectroscopy.The order of proton affinities is identical with the solution basicity order reported earlier.Thus, increasing steric constraint decreases the proton affinity of the phosphorus lone pair in phosphites.Moreover, the phosphorus lone pair in monocyclic six-membered-ring phosphites is more basic in the axial than in the equatorial position.Adiabatic ionization potentials are obtained from photoelectron spectra of the phosphites.Increases in ionization potential are found to parallel decreases in proton affinity.This relationship between the ionization potential and proton affinity suggests that the first ionization potential of the phosphites corresponds to ionization from the phosphorus lone pair orbital.These trends are rationalized in terms of changes in the interactions of the oxygen lone pair orbitals with the phosphorus lone pair and ?-bonding orbitals.