28112-58-5

Upstream product

• 28467-42-7 trans-4-t-butylcyclohexanecarbonyl chloride 
• 71-43-2 benzene 
• 107337-26-8 2-tert-Butyl-[1,3]dioxane-5-carbaldehyde 
• 28112-56-3 trans-(4-tert-Butylcyclohexyl)phenylketon 

Downstream Products

• 107337-31-5 trans-2-t-butyl-5-phenylketon-1,3-dioxane 
• 107337-30-4 cis-2-t-butyl-5-phenylketone-1,3-dioxane 
• 107337-48-4 cis 2-t-butyl-5-methyl-5-phenylketone-1,3-dioxane 
• 107337-49-5 trans 2-t-butyl-5-methyl-5-phenylketone-1,3-dioxane 

Relevant academic research and scientific papers

A simple method for the conversion of primary alcohols into terminal olefins

Treatment of benzyl ethers of primary alcohols with n-butyllithium (n-BuLi) afforded terminal olefins in good yield.

Study on the enolization of alkyl of cis and trans 2-tert-5-X-1,3-dioxanes (X =CO2CH3, CHO, COPh, NO2, and CN). Evidence for stereoelectronic control.

Alkylation ot 2-tert-butyl-5-X-1,3-dioxanes (X = CO2CH3,COPh and NO2) was studied.Products resulting from an equatorial approach of the alkylating agent are preferentially formed when X = CO2CH3 and NO2.Also, the cis isomers that have an equatorial hydrog