281211-15-2

Basic information

• Product Name: [5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)
• Synonyms: [5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)
• CAS NO: 281211-15-2
• Molecular Weight: 1133.96
• Mol File: 281211-15-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)(CAS DataBase Reference)
• NIST Chemistry Reference: [5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)(281211-15-2)
• EPA Substance Registry System: [5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)(281211-15-2)

Safety Data

• Hazardous Substances Data: 281211-15-2(Hazardous Substances Data)

Upstream product

• 17610-00-3 3,5-Di-tert-butylbenzaldehyde 
• 15164-44-0 p-(iodophenyl)carboxaldehyde 
• 6018-89-9 nickel(II) acetate tetrahydrate 

Relevant articles and documents

Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions

Mixed cyclotrimerization reactions of diarylacetylenes (tolans) were applied to generate a library of multiple porphyrin-hexaphenylbenzene (HPB) architectures. Successful reactions, which could be influenced by the ratio of tolan starting materials, were

Porphyrin-rylene-diimide-hexabenzocoronene triads

Hexa-peri-hexabenzocoronenes (HBCs), substituted by two different chromophores in an ortho arrangement, were synthesized for the first time and investigated towards their photophysical properties. Rylene-diimide dyes, in particular naphthalene-diimides (NDIs) and perylene-diimides (PDIs), were attached to the HBC as the first, and porphyrins as the second chromophore. Therefore, porphyrin-NDI-HPB as well as porphyrin-PDI-HPB precursors were accessed and converted into the respective HBC derivatives applying oxidative Scholl conditions. UV-vis absorption and fluorescence emission spectroscopy showed interesting photophysical behavior such as energy transfer processes. Particularly, the porphyrin-PDI-HBC displays pronounced absorption features between 330-650 nm, which cover a wide range of the visible spectrum.