28192-52-1Relevant academic research and scientific papers
Lewis Acid and Lewis Base Behaviour of a Tellurium(II) Compound: A Mercury(II) Complex of a Bis-telluride Ligand with a 13-Member Macrocyclic Chelate Ring
AL-Salim, Najih,Hamor, Thomas A.,McWhinnie, William R.
, p. 453 - 455 (1986)
The structure of 1,6-bis-2-butyltellurophenyl-2,5-diazahexa-1,5-diene (1) reveals a weak tellurium-nitrogen interaction giving the tellurium atom an effective co-ordination number of 3; with HgCl2, (1) forms the complex which is monomeric with
Alkyltelluro Substitution Improves the Radical-Trapping Capacity of Aromatic Amines
Poon, Jia-Fei,Yan, Jiajie,Singh, Vijay P.,Gates, Paul J.,Engman, Lars
, p. 12891 - 12903 (2016/08/30)
The synthesis of a variety of aromatic amines carrying an ortho-alkyltelluro group is described. The new antioxidants quenched lipidperoxyl radicals much more efficiently than α-tocopherol and were regenerable by aqueous-phase N-acetylcysteine in a two-phase peroxidation system. The inhibition time for diaryl amine 9 b was four-fold longer than recorded with α-tocopherol. Thiol consumption in the aqueous phase was found to correlate inversely to the inhibition time and the availability of thiol is the limiting factor for the duration of antioxidant protection. The proposed mechanism for quenching of peroxyl radicals involves O-atom transfer from peroxyl to Te followed by H-atom transfer from amine to alkoxyl radical in a solvent cage.
Synthesis and Reactions of 1,6-Bis(2-butyltellurophenyl)-2,5-diazahexa-1,5-diene and Related Compounds. The Crystal and Molecular Structures of 2-(Butyldichlorotelluro)benzaldehyde and Bis Ditelluride
Abid, Khalid Y.,Al-Salim, Najih I.,Greaves, Martin,McWhinnie, William R.,West, Antony A.,Hamor, Thomas A.
, p. 1697 - 1704 (2007/10/02)
The synthesis of 1,6-bis(2-butyltellurophenyl)-2,5-diazahexa-1,5-diene and related compounds is reported.Reaction with halogenating reagents leads to rupture of the Te-Bu bond and the isolation of new organotellurium mono- and tri-halides stabilised via c
