282094-27-3

Upstream product

• 2873-29-2 D-glucal triacetate 
• 13035-12-6 3,4,6-tri-O-acetyl-1,2-dideoxy-D-glucopyranose 
• 282094-22-8 ((2R,3S,4R)-3,4-Bis-methoxymethoxy-tetrahydro-pyran-2-ylmethoxy)-tert-butyl-dimethyl-silane 
• 282094-23-9 ((2R,3S,4R)-3,4-Bis-methoxymethoxy-tetrahydro-pyran-2-yl)-methanol 
• 212120-61-1 (2R,3S,4R)-2-(((tert-butyldimethylsilyl)oxy)methyl)tetrahydro-2H-pyran-3,4-diol 
• 3971-47-9 (3S,4R)-dihydroxy-(2R)-(hydroxymethyl)tetrahydropyran 
• 282094-26-2 ((2S,3S,4R)-3,4-Bis-methoxymethoxy-tetrahydro-pyran-2-yl)-phenyl-methanone 

Downstream Products

• 282094-39-7 (2R,3S,4R)-2-((R)-Hydroxy-phenyl-methyl)-tetrahydro-pyran-3,4-diol 

Relevant academic research and scientific papers

Design of a new bifunctional asymmetric catalyst from carbohydrates: Application to catalytic asymmetric cyanosilylation of aldehydes and acetophenone

A new active Lewis acid-Lewis base bifunctional asymmetric catalyst 7 was developed using carbohydrate as a scaffold and this catalyst was applied to the asymmetric cyanosilylation of aldehydes and acetophenone. The β-Ph group at the 6-position of 7 was found to be important for a high asymmetric induction (up to 80% ee) by bringing the Al and the phosphine oxide at optimum positions for a dual activation of carbonyl compounds and TMSCN. (C) 2000 Elsevier Science Ltd.