282525-99-9

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 282526-14-1 methyl 2-deoxy-2-N-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl]amino-1-thio-β-D-glucopyranoside 
• 212394-16-6 3,4,6-tri-O-acetyl-2-deoxy-2-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-ethylamino]-α-D-glucopyranosyl bromide 
• 212394-19-9 methyl 3,4,6-tri-O-acetyl-2-deoxy-2-N-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl]amino-1-thio-β-D-glucopyranoside 
• 100-52-7 benzaldehyde 
• 887402-05-3 methyl 6-O-tert-butyldiphenylsilyl-2-deoxy-2-N-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl]amino-1-thio-β-D-glucopyranoside 
• 212394-22-4 2-Deoxy-2-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethylamino]-1-thio-3,4,6-tri-O-acetyl-β-D-glucopyranose 
• 1078691-95-8 (+)-D-glucosamine hydrochloride 
• 1755-15-3 2-acetyldimedone 
• 887402-06-4 methyl 2-deoxy-2-N-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl]amino-6-O-trityl-1-thio-β-D-glucopyranoside 
• 412036-89-6 1,3,4,6-tetra-O-acetyl-2-deoxy-2-N-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl]amino-D-glucopyranose 

Downstream Products

• 282526-00-5 methyl 4,6-O-benzylidene-3-O-(p-chlorobenzoyl)-2-deoxy-2-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethylamino]-1-thio-β-D-glucopyranoside 
• 887402-03-1 methyl 4,6-O-benzylidene-2-deoxy-2-N-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl]amino-3-O-(4-phenylbenzoyl)-1-thio-β-D-glucopyranoside 
• 357399-53-2 methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-4,6-bis-O-(methanesulfonyl)-1-thio-β-D-glucopyranoside 
• 357399-52-1 methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-1-thio-β-D-glucopyranoside 

Relevant academic research and scientific papers

Dde as a protecting group for carbohydrate synthesis

Oligosaccharide synthesis using aminosugars requires the presence of a suitable amino protecting group. A number of protecting groups are currently used, and while many display favorable properties, most agents available still suffer from certain disadvan

Protecting groups for carbohydrate synthesis

The invention provides collections of orthogonally-protected monosaccharides as universal building blocks for the synthesis of glycoconjugates of non-carbohydrate molecules, neo-glycoconjugates and oligosaccharides. This orthogonal protection strategy all

Conversion of glucosamine to galactosamine and allosamine derivatives: Control of inversions of stereochemistry at C-3 and C-4

The reactions of sodium benzoate with a series of trimesylates derived from glucosamine have been examined in an attempt to gain facile access to galactosamine analogues. Trimesylate 17, in which the amino group was protected as a phthalimide, underwent double displacement at positions 4 and 6 to give the dibenzoate 18 with the desired galactosamine configuration. In contrast, trimesylates 21 and 27, in which the amino groups were protected as acetamides, unexpectedly underwent double displacement at positions 3 and 6, giving products 22 and 28, respectively, with allosamine configurations.