28286-77-3Relevant academic research and scientific papers
Pd-catalyzed carbonylation for the construction of tertiary and quaternary carbon centers with sp3 carbon partners
Lu, Wei,Li, Yang,Wang, Chao,Xue, Dong,Chen, Jian-Gang,Xiao, Jianliang
supporting information, p. 5243 - 5249 (2014/07/08)
The first examples of a Pd-catalyzed carbonylation of aryl boronic acids with sp3 carbon partners are presented. Various boronic acids were shown to react with 1,3-diesters and 1,3-diketones to afford structurally unique carbonyl compounds. By
Bleach precursors
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, (2008/06/13)
A class of malonates having the structure: wherein:, m is an integer from 0 to 1, m1 is an integer from 0 to 4;, R1 is a C1-C20 radical selected from the group consisting of alkyl, cycloalkyl, alkenyl, cycloalkenyl, phenyl
ACYLATION OF ACTIVE METHYLENE COMPOUNDS VIA PALLADIUM COMPLEX-CATALYZED CARBONYLATIVE CROSS-COUPLING OF ORGANIC HALIDES
Kobayashi, Toshi-aki,Tanaka, Masato
, p. 4745 - 4748 (2007/10/02)
New procedures for acylation of active methylene compounds via palladium complex-catalyzed carbonylation of organic halides are disclosed.
A NEW METHOD FOR ACYLATION OF ENOLATES BY MEANS OF DIALKYL ACYLPHOSPHONATES AS ACYLATING AGENTS
Sekine, Mitsuo,Kume, Akiko,Nakajima, Masashi,Hata, Tsujiaki
, p. 1087 - 1090 (2007/10/02)
Acylations of various enolates by means of diethyl acylphosphonates were described.For the acylation of acetophenone, lithium bis(trimethylsilyl)amide (LSA) was found to be suitable as the base.The scope and limitation of the benzoylation using diethyl benzoylphosphonates were also described.
