28325-75-9

Basic information

• Product Name: Benzene, ethenyl-, homopolymer, syndiotactic
• Synonyms: Benzene, ethenyl-, homopolymer, syndiotactic;Syndiotactic polystyrene
• CAS NO: 28325-75-9
• Molecular Formula: MW:
• Molecular Weight: 104.15
• Mol File: 28325-75-9.mol
• Article Data: 1442

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, ethenyl-, homopolymer, syndiotactic(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, ethenyl-, homopolymer, syndiotactic(28325-75-9)
• EPA Substance Registry System: Benzene, ethenyl-, homopolymer, syndiotactic(28325-75-9)

Safety Data

• Hazardous Substances Data: 28325-75-9(Hazardous Substances Data)

Upstream product

• 689-97-4 3-buten-1-yne 
• 67-56-1 methanol 
• 96-09-3 styrene oxide 
• 603-35-0 triphenylphosphine 
• 56-23-5 tetrachloromethane 
• 111-34-2 -butyl vinyl ether 
• 60-29-7 diethyl ether 
• 15507-13-8 Sulfuric acid monobutyl ester 
• 3299-05-6 1-ethoxy-1-phenylethane 
• 74-98-6 propane 
• 637-27-4 phenyl propionate 
• 93-92-5 1-phenylethyl acetate 
• 93-96-9 bis(1-phenylethyl)ether 
• 3480-87-3 3-hydroxy-3-phenylpropanoic acid 

Downstream Products

• 39657-33-5 2-methyl-1-phenethyl-aziridine 
• 936-48-1 3-phenyl-4,5-dihydro-1H-pyrazole 
• 4858-35-9 5-phenethylmercapto-3H-[1,3,4]thiadiazole-2-thione 
• 21015-77-0 bis-phenethylmercapto-[1,3,4]thiadiazole 
• 33863-82-0 4-methyl-N-(1-phenylethyl)aniline 
• 70660-38-7 rac-4-methyl-2-sec-phenethylaniline 
• 4799-66-0 2-(1-phenylethoxy)ethanol 
• 78759-31-6 1,2-bis-(1-phenyl-ethoxy)-ethane 
• 4850-49-1 1-phenyl-1,3-propanediol 
• 1608-27-1 1-phenylpenta-1,3-diene 
• 35770-75-3 4-(α-methylbenzyl)-3-methylphenol 
• 108959-42-8 4,6-di(α-methylbenzyl)-3-methylphenol 
• 4333-75-9 1-(4-methoxyphenyl)-1-phenylethene 
• 1694-19-5 E-1-(phenyl)-2-(4'-methoxyphenyl)ethene 

Relevant articles and documents

Photoredox Catalyzed Sulfonylation of Multisubstituted Allenes with Ru(bpy)3Cl2 or Rhodamine B

A highly regio- and stereoselective sulfonylation of allenes was developed that provided direct access to α, β-substituted unsaturated sulfone. By means of visible-light photoredox catalysis, the free radicals produced by p-toluenesulfonic acid reacted with multisubstituted allenes to obtain Markovnikov-type vinyl sulfones with Ru(bpy)3Cl2 or Rhodamine B as photocatalyst. The yield of this reaction could reach up to 91%. A series of unsaturated sulfones would be used for further transformation to some valuable compounds.

Mild and efficient desulfurization of thiiranes with MoCl5/Zn system

Desulfurization of a variety of thiiranes to alkenes occurs chemoselectively in high yields upon treatment with MoCl5/Zn system under mild conditions. The new methodology demonstrates high functional group tolerance toward chloro, bromo, fluoro, methoxy, ester, ether and keto groups.

Oxidative Alkenylation of Arenes Using Supported Rh Materials: Evidence that Active Catalysts are Formed by Rh Leaching

This work focuses on the synthesis of supported Rh materials and study of their efficacy as pre-catalysts for the oxidative alkenylation of arenes. Rhodium particles supported on silica (Rh/SiO2; ～3.6 wt% Rh) and on nitrogen-doped carbon (Rh/NC