28421-57-0Relevant articles and documents
A CONVENIENT SYNTHESIS OF 1α,25-DIHYDROXY-28-NORVITAMIN-D2
Moriarty, Robert M.,Kim, Joonggon,Penmasta, Raju
, p. 3741 - 3744 (1992)
The title compound was synthesized via the Julia olefination using ring B-diene protected 3β-hydroxy-23,24-bisnorchola-5,7-diene-22-al acetate and the side-chain synthon 2-methyl-4-phenylsulfonyl-2-(tetrahydropyranyloxy)butane.Ring B-deprotection, photoly
New Intermediates in Synthesis of Provitamins D
Litvinovskaya,Koval',Khripach
, p. 1442 - 1446 (2007/10/03)
The first synthesis of provitamins possessing isoxazole ring in the side chain is described. The synthesis is performed from ergosterol acetate via steroid C22-nitrile oxide by means of 1,3-dipolar cycloaddition of the latter to low-molecular a
STARFISH SAPONINS VI - UNIQUE 22,23-EPOXISTEROIDAL CYCLIC GLYCOSIDES, MINOR CONSTITUENTS FROM ECHINASTER SEPOSITUS
Riccio, R.,Simone, E. De,Dini, A.,Minale, L.,Pizza, C.,et al.
, p. 1557 - 1560 (2007/10/02)
On the basis of comparative 1H- and 13C-n.m.r. data, the structures of the minor saponins from the starfish Echinaster sepositus have been elucidated to be 2-4.They closely resemble 1, the major saponin from the same starfish, and, in addition to the cyclic trisaccharide moiety bridging C-3 and C-6 of the steroid, include epoxide functionalities in the steroidal side-chains.