28435-21-4Relevant academic research and scientific papers
KRISTALLSTRUKTUR VON BIS(DIETHYLDITHIOCARBAMATO)-PHENYLPHOSPHAN UND SYNTHESE EINIGER MONO- UND BIS(DIORGANYLDITHIO-CARBAMATO)PHOSPHANE
Wieber, Markus,Burschka, Christian,Bauer, Brend
, p. 157 - 166 (2007/10/02)
By reaction of organylchlorophosphanes with sodium dithiocarbamates compounds of the type RP(S2CNR'2)2 with R=CH3, C6H5; R'=CH3, C2H5, CH(CH3)2, C6H5 and of the type (C6H5)2PS2CNR'2 with R'=CH3, CH(CH3)2 as well as compound 2 are obtained.The crystal structure of C6H5P(S2CN(C2H5)2)2 shows that the trend from bidentate to monodentate bonding of the dithiocarbamate ligands in the homologous series RE(S2CN(C2H5)2)2; E=Bi, Sb, As, P is contiuned for E=P.Key words: Crystal structure; bis(diethyldithiocarbamato)phenylphosphane; dialkyldithiocarbamatodiphenylphosphanes; bis(diorganyldithiocarbamato)organylphosphanes; nucleophilic displacement; bidentate bonding
