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The chemical compound "6-[({2-[(2-{[(E)-(6-oxocyclohexa-2,4-dien-1-ylidene)methyl]amino}ethyl)amino]ethyl}amino)methylidene]cyclohexa-2,4-dien-1-one" is a complex organic molecule with a highly branched structure. It features a cyclohexa-2,4-dien-1-one core, which is a six-membered ring with alternating double bonds and a carbonyl group. The molecule is further characterized by a series of aminoethyl groups attached to the core, with one of these groups having a (E)-configuration, indicating the geometric arrangement of the double bond. The compound's complexity arises from the multiple layers of amide and amine functionalities, which are connected through methylene bridges. This structure is indicative of a conjugated system, which can influence its electronic properties and reactivity. The compound's name reflects its intricate arrangement of atoms and bonds, making it a challenging target for synthesis and a subject of interest in organic chemistry due to its potential applications in various fields, such as pharmaceuticals or materials science.

2851-60-7

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2851-60-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2851-60-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,8,5 and 1 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 2851-60:
(6*2)+(5*8)+(4*5)+(3*1)+(2*6)+(1*0)=87
87 % 10 = 7
So 2851-60-7 is a valid CAS Registry Number.

2851-60-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (6E)-6-[[2-[2-[[(E)-(6-oxocyclohexa-2,4-dien-1-ylidene)methyl]amino]ethylamino]ethylamino]methylidene]cyclohexa-2,4-dien-1-one

1.2 Other means of identification

Product number -
Other names N,N'-bis(3-salicylidenaminopropyl)amine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2851-60-7 SDS

2851-60-7Relevant academic research and scientific papers

Synthesis, crystal structures, catalytic application and antibacterial activities of Cu(II) and Zn(II) complexes bearing salicylaldehyde-imine ligands

Liu, Chao,Chen, Ming-Xing,Li, Ming

, (2020)

Three novel copper(II) and zinc(II) complexes based on salicylaldehyde-imine ligands, namely [Cu(HL1)(CH3CH2OH)]·(CH3COO) (1), [Zn3(HL1)2(CH3COO)4] (2), and [Zn2(L2)]·

Study of Synthesis and Corrosion Inhibition of Novel Mannich and Schiff Bases on Carbon Steel in Acid Solution

Fu, Luoping,Yi, Fei,Zeng, Bo,Hu, Chao,Li, Jianbo

, p. 499 - 509 (2018)

In this paper, a Schiff base (SB-1) and derivatives (SB-2 and SB-3) was synthesized and characterized by IR and 1H NMR methods, the corrosion efficiency and mechanism of carbon steel in 1: 1 hydrochloric acid was obtained by weight loss measure

An oxo-bridged dinuclear vanadium(V) complex of N,N'-bis(salicylidene)-1,5- diimino-3-azapentane: Synthesis and structure

Wang, Fu-Ming

, p. 1386 - 1389 (2012)

The reaction of vanadyl acetylacetonate with N,N'-bis (salicylidene)-1,5- diimino-3-azapentane (H2SDA) affords an oxo-bridged dinuclear Schiff base vanadium(V) complex, [VO2(HSDA)]2. The structure of the complex was charac

A novel homodinuclear manganese(III) complex with N,N′- bis(salicylidene)diethylenetriamine: Synthesis, structure and catalytic activity

Hosseini-Monfared, Hassan,Alavi, Sohaila,Mayer, Peter

, p. 89 - 95 (2014)

A novel chloride bridged dinuclear manganese(III) complex was prepared and its structure established by X-ray diffraction analysis. The complex showed high selectivity in H2O2 promoted oxidation of cyclohexane and cyclic alkenes. Und

Imidazole and imine coated ZnO nanoparticles for nanomolar detection of Al(III) and Zn(II) in semi-aqueous media

Sharma, Hemant,Singh, Narinder,Jang, Doo Ok

, p. 6623 - 6626 (2014)

Imidazole and imine-linked dipodal receptors were decorated on the surface of ZnO nanoparticles. Cation binding assays of these chemosensors showed that receptors 5 and 6 had high selectivity for Al(III) and Zn(II) ions, respectively. The detection limit

One-pot metal template synthesis, crystal structures and spectroscopic properties of self-assembled rare earth metal ion complexes of salicylaldimine ligands

Pospieszna-Markiewicz, Izabela,Radecka-Paryzek, Wanda,Kubicki, Maciej,Hnatejko, Zbigniew

, p. 409 - 414 (2016)

The one-step metal-promoted condensation reaction of salicylaldehyde with diethylenetriamine in the presence of rare earth metal ions carried out in the same experimental conditions produces two types of salicylaldimine complexes. The compounds were chara

One-pot synthesis of 2,5-diformylfuran from fructose using a magnetic bi-functional catalyst

Mittal, Neha,Nisola, Grace M.,Malihan, Lenny B.,Seo, Jeong Gil,Kim, Hern,Lee, Seong-Poong,Chung, Wook-Jin

, p. 25678 - 25688 (2016)

A magnetic bi-functional WO3HO-VO(salten)-SiO2@Fe3O4 nanocatalyst was prepared to directly synthesize 2,5-diformylfuran (2,5-DFF) from fructose. The chlorosilylated SiO2@Fe3O4 (Cl-SiO2@Fe3O4) nanoparticles served as the platform for the two functionalities. Tungstic acid was generated via protonation of sodium tungstate, which was directly attached on the platform via nucleophilic -Cl displacement. Meanwhile, oxovanadium was complexed with a salten ligand which was functionalized on the Cl-SiO2@Fe3O4. Characterization results confirmed the successful preparation of the WO3HO-VO(salten)-SiO2@Fe3O4 nanocatalyst. Under the optimal one-pot system, tungstic acid-mediated fructose dehydration afforded 82% 5-hydroxymethylfurfural (5-HMF) in 1 h. Upon co-oxidant H2O2 addition, in situ 5-HMF oxidation by the activated oxoperoxovanadium species produced 71% of 2,5-DFF after 15 h under ambient air. The stability of 5-HMF formation was found critical to 2,5-DFF production. Aside from the catalytic efficiency and process simplicity, the WO3HO-VO(salten)-SiO2@Fe3O4 nanocatalyst was readily retrieved magnetically and re-used multiple times with marginal losses in its activity.

Zn2+ and EDTA Cooperative Switchable Nanofluidic Diode Based on Asymmetric Modification of Single Nanochannel

Sun, Yao,Zhang, Fan,Sun, Zhongyue,Song, Miaomiao,Tian, Demei,Li, Haibing

, p. 4355 - 4358 (2016)

Design and fabrication of smart switchable nanofluidic diodes remains a challenge in the life and materials sciences. Here, we present the first example of a novel Zn2+/EDTA switchable nanofluidic diode system based on the control of one-side o

Green synthesis of a vanadium(V) Schiff base complex by grinding method: study on its catalytic and anti-bacterial activity

Boruah, Jeena Jyoti,Bhatt, Zankhana S.,Nathani, Chirag R.,Bambhaniya, Vaishali J.,Guha, Ankur Kanti,Das, Siva Prased

, p. 2055 - 2068 (2021/06/27)

A facile protocol was developed for the green synthesis of a Schiff base and its vanadium(V) complex. The compounds were derived from salicylaldehyde, diethylenetriamine and vanadyl sulfate by applying grinding method to overcome environmental issues with solvents. The reactions took place rapidly and products were isolated pure. The compounds were characterized with elemental, EDX, mass spectrometry, magnetic susceptibility, molar conductance, UV-vis, FTIR and NMR analysis. The synthesized vanadium(V) complex was an efficient and selective catalyst towards oxidation of organic sulfides and alcohols. The oxidation reactions were conducted under microwave irradiation as well as conventional heating. A reaction mechanism has been proposed for the catalytic oxidation reactions. The mechanism was further established by using GAUSSIAN16 suite. The complex also showed good anti-bacterial activity against Gram-positive and Gram-negative bacteria.

Pd salen complex@CPGO as a convenient, effective heterogeneous catalyst for Suzuki–Miyaura and Heck–Mizoroki cross-coupling reactions

Ghabdian, Mahdieh,Nasseri, Mohammad Ali,Allahresani, Ali,Motavallizadehkakhky, Alireza

, p. 1713 - 1728 (2018/05/25)

A Pd(II) Schiff base complex supported on graphene oxide nanosheets (Pd(II) salen@CPGO) has been synthesized and characterized by FT-IR, ICP-AES, XRD, SEM/EDX and TEM. The synthesized nanocatalyst has been found to be an efficient heterogeneous catalyst for Suzuki–Miyaura and Heck–Mizoroki coupling reactions. Pd(II) salen@CPGO could be separated and recovered easily from the reaction mixture and recycled several times without a discernible decrease in its catalytic activity. The construction of a solid sheet-supported Pd catalyst would be expected to be a promising system to perform heterogeneous catalytic reactions.

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