28609-00-9

Upstream product

• 28750-98-3 (benzoyl-methyl-amino)-(4-methoxy-phenyl)-acetic acid 

Downstream Products

• 117712-09-1 2-(4-methoxyphenyl)-1-methyl-4,5-diphenylpyrrole-3-carboxylic acid 
• 117712-10-4 5-(4-methoxyphenyl)-1-methyl-2,4-diphenylpyrrole-3-carboxylic acid 
• 32494-28-3 β--β-<4-methoxyphenyl>-styrol 
• 66550-89-8 4-(4-methoxy-phenyl)-3-methyl-2-phenyl-5-sulfo-thiazolium betaine 
• 130485-17-5 2-(4-Methoxy-phenyl)-1-methyl-4,5-diphenyl-2,3-dihydro-1H-pyrrole-3-carbonitrile 
• 130485-10-8 2-(4-Methoxy-phenyl)-1-methyl-4,5-diphenyl-1H-pyrrole-3-carbonitrile 
• 113545-99-6 5-(4-Methoxy-phenyl)-1-methyl-2-phenyl-1H-[1,3]azaphosphol-4-ol 
• 130485-14-2 5-(4-Methoxy-phenyl)-1-methyl-2,4-diphenyl-1H-pyrrole-3-carboxylic acid methyl ester 
• 113545-94-1 5-(4-Methoxy-phenyl)-1-methyl-2-phenyl-4-trimethylsilanyloxy-1H-[1,3]azaphosphole 
• 66380-11-8 4-(4-methoxy-phenyl)-3-methyl-2-phenyl-5-thioxo-4,5-dihydro-thiazolium betaine 

Relevant academic research and scientific papers

Regioselectivity in the 1,3-dipolar cycloaddition of muenchnones with two electrophilic alkynes. Attempt of rationalization.

The 1,3-dipolar cycloaddition reaction of several unsymmetrically substituted muenchnones with methyl propiolate 3a and with methyl 3-phenylpropiolate 3b has been examined.The reaction generally proceeds with formation of mixtures of both possible regioisomeric pyrroles.The dipolarophile 3b is more selective than 3a in accordance with the literature.Sustmann's variation-perturbation theory could not account for the observed regioselectivities, this theory gives correct predictions with alkenes as we have shown recently. 1,3-cycloaddition / muenchnones / pyrroles / regioselectivity