2863-49-2Relevant academic research and scientific papers
Nickel-Catalyzed Highly Enantioselective Hydrogenation of β-Acetylamino Vinylsulfones: Access to Chiral β-Amido Sulfones
Long, Jiao,Gao, Wenchao,Guan, Yuqing,Lv, Hui,Zhang, Xumu
supporting information, p. 5914 - 5917 (2018/09/25)
The nickel/(S)-Binapine complex was found to be an efficient catalyst for asymmetric hydrogenation of β-acetylamino vinylsulfones to afford chiral β-Amido sulfones with excellent yields and enantioselectivities (up to 95% yields and >99% ee). This protocol has good compatibility with a series of substituted (Z)-β-acetylamino vinylsulfones or Z/E isomeric mixtures. A gram-scale reaction has also been achieved in the presence of a 0.2 mol % catalyst loading.
New Synthetic Methods 4 : Mild Onephase Oxidation of Sulfides and Sulfoxides to Sulfones
Scholz, Dieter
, p. 241 - 244 (2007/10/02)
The mild oxidation of sulfides and sulfoxides to sulfones with benzyltriethylammonium permanganate in organic solvents is described. - Keywords: Benzyltriethylammonium permanganate; Sulfides; Sulfones; Sulfoxides
