2865-70-5

Basic information

• Product Name: 10-chloro-10H-phenoxarsine
• Synonyms: 10-chloro-10H-phenoxarsine;10-CHLOROPHENOXYARSINE;DID95;10-Chloro-10H-dibenz-1,4-oxarsine
• CAS NO: 2865-70-5
• Molecular Formula: C₁₂H₈AsClO
• Molecular Weight: 278.56592
• EINECS: 220-684-6
• Mol File: 2865-70-5.mol
• Article Data: 2

Chemical Properties

• Melting Point: 122°C
• Boiling Point: 365.1°Cat760mmHg
• Flash Point: 174.8°C
• Appearance: /solid
• Density: g/cm³
• Vapor Pressure: 3.38E-05mmHg at 25°C
• CAS DataBase Reference: 10-chloro-10H-phenoxarsine(CAS DataBase Reference)
• NIST Chemistry Reference: 10-chloro-10H-phenoxarsine(2865-70-5)
• EPA Substance Registry System: 10-chloro-10H-phenoxarsine(2865-70-5)

Safety Data

• Hazardous Substances Data: 2865-70-5(Hazardous Substances Data)

Usage

Safety Profile

Poison by ingestion. See also ARSINE and ARSENIC COMPOUNDS. When heated to decomposition it emits very toxic fumes of As and Cl-.

InChI:InChI=1/C12H8AsClO/c14-13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)13/h1-8H

Upstream product

• 101-84-8 diphenylether 
• 860602-58-0 (2-phenoxy-phenyl)-arsonic acid 
• 139888-60-1 o,o'-bis(dichloroarseno)diphenyl oxide 
• 4431-23-6 dichloro-(2-phenoxy-phenyl)-arsine 

Downstream Products

• 58-36-6 10,10,oxybisphenoxarsine 
• 39548-41-9 10-cyclohexyl-10H-phenoxarsine 
• 39548-43-1 10-benzyl-10H-phenoxarsine 
• 70841-21-3 10-(4-trifluoromethyl-phenyl)-10H-phenoxarsine 
• 55369-43-2 10-(4-ethoxy-phenyl)-10H-phenoxarsine 
• 39548-31-7 10-phenylethynyl-10H-phenoxarsine 
• 55369-39-6 10-biphenyl-4-yl-10H-phenoxarsine 
• 2703-34-6 10-Phenoxarsin-dimethyl-dithiocarbamidsaeure-ester 
• 55369-42-1 10-(3-methoxy-phenyl)-10H-phenoxarsine 
• 4227-32-1 10-iodophenoxarsine 

Relevant articles and documents

Synthesis and structural characterization of phenoxarsin-10-yl dithiocarbamates. O(C6H4)2AsS2CN(CH2CH2)2, a compound containing an asymmetric mononuclear biconnective 1,1-dithiolato ligand

Phenoxarsin-10-yl dithiocarbamates O(C6H4)2AsS2CX (X = NMe2, NEt2, N(CH2CH)2, N(CH2CH2)2 or N) have been prepared by the reaction between O(C6H4)2AsCl and sodium dithiocarbamates.The compounds were characterized by IR, mass and NMR (1H and 13C) spectroscopy.The molecular structure of O(C6H4)2AsS2CN(CH2CH2)2 was determined using single-crystal X-ray diffraction.The compound is monomeric and contains an asymmetric monometallic biconnective dithiocarbamato unit (As-S(1), 2.277(1), Angstroem; As...S(2), 3.183(3) Angstroem).The double-bond character of the C-N bond (1.318(5) Angstroem) is in agreement with the NMR data.The dihedral angle (155.2 deg) of the phenoxarsine moiety is almost unaffected by substitution of chlorine by the dithiocarbamato ligand. Keywords: Arsenic; Dithiocarbamates; Phenoxarsine; Group 15