286838-06-0

Basic information

• Product Name: (2R)-2-[(1S,2R,4R)-2-tert-butyldimethylsilyloxy-4-methylcyclohexyl]propyl ethanethioate
• CAS NO: 286838-06-0
• Molecular Weight: 344.634
• Mol File: 286838-06-0.mol

Chemical Properties

• CAS DataBase Reference: (2R)-2-[(1S,2R,4R)-2-tert-butyldimethylsilyloxy-4-methylcyclohexyl]propyl ethanethioate(CAS DataBase Reference)
• NIST Chemistry Reference: (2R)-2-[(1S,2R,4R)-2-tert-butyldimethylsilyloxy-4-methylcyclohexyl]propyl ethanethioate(286838-06-0)
• EPA Substance Registry System: (2R)-2-[(1S,2R,4R)-2-tert-butyldimethylsilyloxy-4-methylcyclohexyl]propyl ethanethioate(286838-06-0)

Safety Data

• Hazardous Substances Data: 286838-06-0(Hazardous Substances Data)

Upstream product

• 7786-67-6 isopulegol 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 507-09-5 tiolacetic acid 
• 80868-19-5 tert-butyldimethyl(((1R,2S,5R)-5-methyl-2-(prop-1-en-2-yl)cyclohexyl)oxy)silane 

Downstream Products

• 286838-32-2 (R)-2-[(1S,2R,4R)-2-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-cyclohexyl]-propane-1-thiol 

Relevant articles and documents

Synthesis of thiabicyclic heterocycles through free radical cyclization of β-thioacrylates

8-Aza-3-thiabicyclo[4.3.0]nonanes 7 and 8, 3-thiabicyclo[4.4.0]decanes 18, and 8-thiabicyclo[4.3.0]nonanes 31 were obtained from monocyclic precursors through free radical cyclizations involving a β-thioacrylate system as radical acceptor and a thionocarbonate as radical precursor. Oxidative sulfur extrusion in 3-thiabicyclo[4.4.0]decanes 18 afforded methyl (2-isopropenyl-5-methylcyclohexyl)-2-propenoates 35. (C) 2000 Elsevier Science Ltd.