286958-08-5

Upstream product

• 286958-06-3 (R)-1,4-Dioxa-spiro[4.5]decane-2-carboxylic acid (2S,3R)-2-(2-benzyloxy-ethyl)-tetrahydro-pyran-3-yl ester 
• 286958-05-2 (2S,3R)-2-(2-Benzyloxy-ethyl)-tetrahydro-pyran-3-ol 
• 242808-58-8 (2S,3R)-2-(2-propenyl)-3-hydroxyoxane 
• 100-39-0 benzyl bromide 
• 286958-07-4 (R)-2-{1-[(2S,3R)-2-(2-Benzyloxy-ethyl)-tetrahydro-pyran-3-yloxy]-vinyl}-1,4-dioxa-spiro[4.5]decane 

Relevant academic research and scientific papers

Asymmetric synthesis of the A-ring part of ciguatoxin by the strategy based on diastereoselective hydroboration and ring closing metathesis

Asymmetric synthesis of the A-ring part of a marine toxin ciguatoxin (CTX1 B) was achieved by the strategy based on ring closing metathesis (RCM), where introduction of the C5 asymmetric center was performed by diastereocontrolled hydroboration of a vinyl