287178-29-4

Basic information

• Product Name: (4R)-3-((4'R,5'R)-cyclohexene-4'-carbonyl)-4-(phenylmethyl)-2-oxazolidinone
• CAS NO: 287178-29-4
• Molecular Weight: 299.37
• Mol File: 287178-29-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4R)-3-((4'R,5'R)-cyclohexene-4'-carbonyl)-4-(phenylmethyl)-2-oxazolidinone(CAS DataBase Reference)
• NIST Chemistry Reference: (4R)-3-((4'R,5'R)-cyclohexene-4'-carbonyl)-4-(phenylmethyl)-2-oxazolidinone(287178-29-4)
• EPA Substance Registry System: (4R)-3-((4'R,5'R)-cyclohexene-4'-carbonyl)-4-(phenylmethyl)-2-oxazolidinone(287178-29-4)

Safety Data

• Hazardous Substances Data: 287178-29-4(Hazardous Substances Data)

Upstream product

• 151215-01-9 (4R)-3-((E)-2-BUTENOYL)-4-(PHENYLMETHYL)-2-OXAZOLIDINONE 
• 106-99-0 buta-1,3-diene 
• 40217-17-2 (R)-4-(phenylmethyl)-2-oxazolidinone 

Downstream Products

• 287178-38-5 ethyl (1R,2R,5S)-5-hydroxy-2-methyl-1-carboxylate 
• 287178-33-0 ethyl (1R,2R,5R)-5-hydroxy-2-methyl-1-carboxylate 
• 287178-36-3 ethyl (1R,2R)-2-methyl-5-one-1-carboxylate 
• 92344-71-3 (-)-(1R,6R)-6-methyl-3-cyclohexenecarboxylic acid 

Relevant articles and documents

Enantioselective synthesis of ceralure B1, ethyl cis-5-iodo-trans-2- methylcyclohexane-1-carboxylate

Ethyl (1R, 2R, 5R)-5-iodo-2-methylcyclohexane-1-carboxylate is a potent attractant for the Mediterranean fruit fly. This compound was stereoselectively synthesized on a multigram scale in nine steps in 15% yield. Key steps of the synthesis involved an asymmetric Diels-Alder reaction, iodolactonization, stereoselective reduction of the carbonyl, and inversion of configuration with iodide. (C) 2000 Elsevier Science Ltd.