287483-41-4

Basic information

• Product Name: (4S,5S)-4-(tert-butyldiphenylsilanyloxy)-5-pentyldihydrofuran-2-one
• Synonyms: (4S,5S)-4-(tert-butyldiphenylsilanyloxy)-5-pentyldihydrofuran-2-one
• CAS NO: 287483-41-4
• Molecular Weight: 410.629
• Mol File: 287483-41-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4S,5S)-4-(tert-butyldiphenylsilanyloxy)-5-pentyldihydrofuran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,5S)-4-(tert-butyldiphenylsilanyloxy)-5-pentyldihydrofuran-2-one(287483-41-4)
• EPA Substance Registry System: (4S,5S)-4-(tert-butyldiphenylsilanyloxy)-5-pentyldihydrofuran-2-one(287483-41-4)

Safety Data

• Hazardous Substances Data: 287483-41-4(Hazardous Substances Data)

Upstream product

• 36781-67-6 methyl non-3-enoate 
• 111-71-7 heptanal 
• 36781-67-6 methyl (trans-3-nonenoate) 
• 28163-88-4 (E)-non-3-enoic acid 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 165605-79-8 (4S,5S)-4,5-dihydro-4-hydroxy-5-pentyl-2-(3H)-furanone 

Downstream Products

• 1422267-58-0 C₂₅H₃₈O₃Si 
• 1422267-50-2 C₃₁H₄₈O₃Si₂ 
• 1422267-52-4 C₃₆H₅₀O₃Si₂ 
• 1422267-54-6 C₂₈H₃₉BrO₃Si 
• 287483-42-5 (E)-(5S,6S)-5-(tert-Butyl-diphenyl-silanyloxy)-6-hydroxy-undec-2-enoic acid methyl ester 
• 329010-29-9 ethyl (2E)(5S,6S)-5-(tert-butyldiphenylsilanyloxy)-6-hydroxydec-2-enoate 
• 287483-51-6 (1S)-1-[(4S,5S,2S)-4-(tert-butyldiphenylsilanyloxy)-5-pentyltetrahydrofuran-2-yl]-dec-9-en-1-ol 
• 287483-48-1 (1R)-1-[(4S,5S,2R)-4-(tert-butyldiphenylsilanyloxy)-5-pentyltetrahydrofuran-2-yl]-dec-9-en-1-ol 
• 287483-49-2 (2R)-2-[(4S,5S,2S)-4-(tert-butyldiphenylsilanyloxy)-5-pentyltetrahydrofuran-2-yl]-2-methanesulfonyloxy-ethyl benzoate 
• 287483-46-9 (2S)-2-[(4S,5S,2R)-4-(tert-butyldiphenylsilanyloxy)-5-pentyltetrahydrofuran-2-yl]-2-methanesulfonyloxy-ethyl benzoate 
• 1053616-72-0 Benzoic acid (S)-2-[(2R,4S,5S)-4-(tert-butyl-diphenyl-silanyloxy)-5-pentyl-tetrahydro-furan-2-yl]-2-hydroxy-ethyl ester 
• 287483-45-8 (1R)-1-[(4S,5S,2S)-4-(tert-butyldiphenylsilanyloxy)-5-pentyltetrahydrofuran-2-yl]-ethane-1,2-diol 
• 287483-44-7 (1S)-1-[(4S,5S,2R)-4-(tert-butyldiphenylsilanyloxy)-5-pentyltetrahydrofuran-2-yl]-ethane-1,2-diol 
• 287483-43-6 (2E)(5S,6S)-5-(tert-butyldiphenylsilanyloxy)-undec-2-ene-1,6-diol 

Relevant articles and documents

Sakurai reaction of 3,3-bis(silyl) silyl enol ethers with acetals involving selective desilylation of the geminal bis(silane). Concise synthesis of nematocidal oxylipid

3,3-Bis(silyl) silyl enol ethers have been shown to exhibit predominantly Sakurai reactivity, rather than Mukaiyama aldol reactivity, in their Lewis acid promoted reactions with acetals. Starting from a geminal bis(silyl) moiety consisting of two differen

Enantiocontrolled synthesis of C-19 tetrahydrofurans isolated from the marine alga Notheia anomala

The stereocontrolled synthesis of (2S,3S,5R)-5-[(1R)-1-hydroxy-9- decenyl]-2-pentyltetrahydro-3-furanol and (2S,3S,5S)-5-[(1S)-1-hydroxy-9- decenyl]-2-pentyltetrahydro-3-furanol, both isolated from the brown alga Notheia anomala has been achieved. The req