36781-67-6

Basic information

• Product Name: FEMA 3710
• Synonyms: METHYL 3-NONENOATE;METHYL T3 NONENOATE;METHYL TRANS-3-NONENOATE;FEMA 3710;TRANS-NONENOIC ACID METHYL ESTER;Methyltrans-3-nonenoate,98%;Zinc01850695;(E)-Methyl non-3-enoate
• CAS NO: 36781-67-6
• Molecular Formula: C₁₀H₁₈O₂
• Molecular Weight: 170.25
• EINECS: 236-786-9
• Mol File: 36781-67-6.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 212.7 °C at 760 mmHg
• Flash Point: 191 °F
• Appearance: /
• Density: 0.885 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.436(lit.)
• CAS DataBase Reference: FEMA 3710(CAS DataBase Reference)
• NIST Chemistry Reference: FEMA 3710(36781-67-6)
• EPA Substance Registry System: FEMA 3710(36781-67-6)

Safety Data

• WGK Germany: 2
• Hazardous Substances Data: 36781-67-6(Hazardous Substances Data)

Usage

General Description

FEMA 3710 is a chemical compound used in flavor and fragrance manufacturing. It is known for its sweet and fruity odor and is commonly used in food and beverage production. FEMA 3710 is often used as a flavoring agent in products such as candies, baked goods, and beverages, adding a pleasantly sweet and fruity aroma to the finished product. This chemical is classified as safe for use in food and beverages by the Flavor and Extract Manufacturers Association (FEMA).

Upstream product

• 111-71-7 heptanal 
• 16695-14-0 Malonic acid monomethyl ester 
• 67-56-1 methanol 
• 111-66-0 oct-1-ene 
• 201230-82-2 carbon monoxide 
• 4124-88-3 3-nonenoic acid 
• 5927-18-4 trimethyl phosphonoacetate 
• 344332-97-4 (+/-)-trimethyl(1-methoxy-2-pentylcyclopropoxy)silane 

Downstream Products

• 4124-88-3 3-nonenoic acid 
• 10339-61-4 3-nonene-1-ol 
• 287483-41-4 (4S,5S)-4-(tert-butyldiphenylsilanyloxy)-5-pentyldihydrofuran-2-one 
• 1422267-58-0 C₂₅H₃₈O₃Si 
• 1422267-50-2 C₃₁H₄₈O₃Si₂ 
• 1422267-52-4 C₃₆H₅₀O₃Si₂ 
• 1422267-54-6 C₂₈H₃₉BrO₃Si 
• 287483-51-6 (1S)-1-[(4S,5S,2S)-4-(tert-butyldiphenylsilanyloxy)-5-pentyltetrahydrofuran-2-yl]-dec-9-en-1-ol 
• 143-08-8 nonyl alcohol 
• 1541181-05-8 (2R,3S)-5,5-dimethyl-2 pentyltetrahydrofuran-3-ol 
• 10339-61-4 (E)-non-3-en-1-ol 
• 28163-88-4 (E)-non-3-enoic acid 
• 287483-42-5 (E)-(5S,6S)-5-(tert-Butyl-diphenyl-silanyloxy)-6-hydroxy-undec-2-enoic acid methyl ester 
• 329010-29-9 ethyl (2E)(5S,6S)-5-(tert-butyldiphenylsilanyloxy)-6-hydroxydec-2-enoate 

Relevant articles and documents

Catalytic Regio- and Enantioselective Oxytrifluoromethylthiolation of Aliphatic Internal Alkenes by Neighboring Group Assistance

Chiral selenide-catalyzed oxytrifluoromethylthiolation of aliphatic internal alkenes by a formally intermolecular strategy is disclosed, affording CF3S 1,3-amino alcohol and 1,3-diol derivatives with high regio-, enantio-, and diastereoselectivities. The reactions are promoted by a neighboring imide or ester group on substrates via a six-membered ring transition state. This assistance strategy is also successfully applied to the regio- and diastereoselective oxyhalofunctionalization of internal alkenes and the conversion of alkynes.

Upgrading castor oil: From heptanal to non-isocyanate poly(amide-hydroxyurethane)s

Intensive research has recently been carried out to synthesize non-isocyanate polyurethanes (NIPUs) from five-membered cyclic carbonates and amines as a sustainable route to industrial relevant polyurethanes. Herein, an activated disubstituted cyclic carbonate and methyl ester containing monomer CE was prepared using castor oil based heptanal and CO2. Good results for the catalytic cycloaddition have been obtained using renewable sugar cane bagasse in combination with TBAB, and this system has been shown to be recyclable. A novel poly(amide-hydroxyurethane) (PAHU) was obtained by bulk ring-opening and amidation polymerization of high reactive CE with 1,6-diaminohexane at low temperature and in absence of catalyst. PAHU contains aliphatic pendant moieties allowing its self-assembling into nanoparticles in aqueous solution, showing potential application in catalysis or drug delivery among other applications.

Electron Transfer Profile of Cyclopropanone Acetals in the Nonirradiated Reaction with Tetracyanoethylene, Chloranil, and Dicyanodichlorobenzoquinone

The donor profiles of cyclopropanone acetals 1 and 2 were examined in the reactions with electron acceptors (TCNE, DDQ, chloranil, and 1-cyanonaphthalene).With TCNE under nonirradiating conditions, an exclusive 2 + 2 cycloaddition took place stereospecifically with monosubstituted acetals 1a-c but nonstereospecifically with disubstituted acetals 1d,e.With quinones, a ring-opening of the cyclopropane and its coupling with the quinone took place to give the C (cyclopropane)-O (quinone) adduct 9 (with chloranil) or 10 (with DDQ), the latter of which underwent the elimination of a phenol to produce unsaturated esters 5 and 6.In addition, the intervention of the C (cyclopropane)-C (quinone) adduct 14 (with chloranil) or 15 (with DDQ), both as the precursor of 5 and 6, was also postulated.With 1-cyanonaphthalene, under photolysis, the cis/trans isomerization of 1 and 2 occured.The results provided evidences that cyclopropanone acetals, in general, are prone to function as donors.The mechanism of the reaction with quinones, in particular, was investigated in detail.