2876-18-8

Basic information

• Product Name: 2-METHOXYPHENAZINE
• Synonyms: 2-METHOXYPHENAZINE
• CAS NO: 2876-18-8
• Molecular Formula: C13H10N2O
• Molecular Weight: 210.2313
• Mol File: 2876-18-8.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 393.8°C at 760 mmHg
• Flash Point: 131.8°C
• Appearance: /
• Density: 1.25g/cm³
• Vapor Pressure: 4.71E-06mmHg at 25°C
• Refractive Index: 1.697
• CAS DataBase Reference: 2-METHOXYPHENAZINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHOXYPHENAZINE(2876-18-8)
• EPA Substance Registry System: 2-METHOXYPHENAZINE(2876-18-8)

Safety Data

• Hazardous Substances Data: 2876-18-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H10N2O/c1-16-9-6-7-12-13(8-9)15-11-5-3-2-4-10(11)14-12/h2-8H,1H3

Upstream product

• 62-53-3 aniline 
• 1427288-36-5 2-(3-methoxyphenyl)-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole 
• 105972-42-7 7-methoxy-1,2,3,4-tetrahydrophenazine 
• 586-96-9 Nitrosobenzene 
• 501-58-6 bis(4-methoxyphenyl)diazene 
• 6319-23-9 1,2-bis(3-methoxyphenyl)diazene 
• 1621867-46-6 7-methoxy-10,11-dihydro-5H-dibenzo[b,e][1,4]diazepine 
• 95-50-1 1,2-dichloro-benzene 
• 583-53-9 2,3-dibromobenzene 
• 1259447-98-7 C₁₃H₁₃ClN₂O 
• 102-51-2 4-methoxy-1,2-phenylenediamine 
• 150-76-5 4-methoxy-phenol 
• 95-54-5 1,2-diamino-benzene 
• 98-95-3 nitrobenzene 

Downstream Products

• 3224-52-0 1-amino-2-methoxyphenazine 
• 303-78-6 2-Methoxyphenazin-5,10-dioxid 
• 4190-95-8 2-hydroxyphenazine 

Relevant articles and documents

Adenine supported hydroxyl-bridged dicopper core as a catalytically competent unit for phenol oxidation

This communication describes crystallographic investigation of a dicopper complex of modified adenine nucleobase containing a Cu2O2 core. This arrangement is remarkably similar to active sites present in some copper-containing redox enzymes. Interestingly, this complex is also competent in catalyzing redox reactions, suggesting the possibility of catalytically competent primitive metal-nucleobase systems.

Direct synthesis of novel quinoxaline derivativesviapalladium-catalyzed reductive annulation of catechols and nitroarylamines

Here, a palladium-catalyzed new hydrogenative annulation reaction of catechols and nitroarylamines, allowing straightforward access to two classes of novel quinoxaline derivatives, is reported. The reaction proceeds with operational simplicity, an easily available catalyst system, and a broad substrate scope, and without the need for pre-functionalization, which offers the potential for further design of new reductive transformations of renewable resources into value-added products.

Reactivity and substituent effects in the cyclization of N-aryl-2-nitrosoanilines to phenazines

Reactivity of variously substituted N-aryl-2-nitrosoanilines in the reaction of cyclization leading to phenazine derivatives, carried out in the presence of N,O-bis(trimethylsilyl)acetamide (BSA), was estimated on the base of the observed reaction times. A strong opposite effect of substituents located at position para to the nitroso group and those located para to the amino group in the side ring was observed. Mechanistic explanation, based on the electronic properties of the substituents and their mesomeric effects, was presented. The usefulness of the obtained data for the designed syntheses of phenazines was exposed.