28765-60-8

Usage

Physical state

Colorless, viscous liquid

Uses

a. Production of polyurethane foams, resins, and adhesives
b. Catalyst for polyurethane polymer formation
c. Corrosion inhibitor
d. pH adjuster
e. Synthesis of lubricants, surfactants, and pharmaceuticals

Properties

a. Excellent foam stability
b. Improved mechanical properties in polyurethane polymers
c. Versatility in various industrial applications

Upstream product

• 110-85-0 piperazine 
• 627-30-5 1-chloro-3-hydroxypropane 
• 13173-24-5 N,N'-bis-allylpiperazine 

Downstream Products

• 86746-12-5 (2,4,5-Trichloro-phenoxy)-acetic acid 3-(4-{3-[2-(2,4,5-trichloro-phenoxy)-acetoxy]-propyl}-piperazin-1-yl)-propyl ester; hydrochloride 
• 86746-13-6 (2,4,6-Trimethyl-phenoxy)-acetic acid 3-(4-{3-[2-(2,4,6-trimethyl-phenoxy)-acetoxy]-propyl}-piperazin-1-yl)-propyl ester; hydrochloride 

Relevant academic research and scientific papers

Method for producing N-alkylpiperazine

PROBLEM TO BE SOLVED: To provide a method for producing N-alkyl piperazines in high yield by selectively alkylating one amino group.SOLUTION: In the method for producing N-alkyl piperazines, piperazines represented by general formula (1) are reacted with a specific alkylating agent in the presence of an acid. In the formula: R-Rare each independently a hydrogen atom, a methyl group, an ethyl group, a 3-8C linear alkyl group or the like, a hydroxyethyl group, a hydroxypropyl group, a dihydroxypropyl group, a methoxy group, an ethoxy group, a phenyl group, a benzyl group, a 2-phenylethyl group, or the like.

HYDROBORATION OF 1,4-DIALLYLPIPERAZINE

Hydroboration of 1,4-diallylpiperazine (I) with triethylamine-borane afforded 5,8-diaza-1,9-diboradispirotetradecane (II). 1,4-Diallylpiperazine dihydrochloride reacted with sodium borohydride to give 1,4-diallylpiperazine-diborane (V).Ethanolysis of II furnished 1,4-bis(3-diethoxyborylpropyl)piperazine (IV).The products of hydroboration of I were subjected to hydrolysis with hydrochloric acid and subsequent oxidation with alkaline hydrogen peroxide and the obtained mixtures were analyzed by gas-liquid chromatography and mass spectrometry.