287976-89-0

Basic information

• Product Name: N-(4-methylbenzoyl)-2-azidobenzamide
• Synonyms: N-(4-methylbenzoyl)-2-azidobenzamide
• CAS NO: 287976-89-0
• Molecular Weight: 280.286
• Mol File: 287976-89-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(4-methylbenzoyl)-2-azidobenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-methylbenzoyl)-2-azidobenzamide(287976-89-0)
• EPA Substance Registry System: N-(4-methylbenzoyl)-2-azidobenzamide(287976-89-0)

Safety Data

• Hazardous Substances Data: 287976-89-0(Hazardous Substances Data)

Upstream product

• 34897-85-3 o-azidobenzoyl chloride 
• 619-55-6 para-methylbenzamide 

Downstream Products

• 18818-41-2 2-(4-methylphenyl)-4(3H)-quinazolinone 

Relevant articles and documents

Isolation, reactivity and intramolecular trapping of phosphazide intermediates in the Staudinger reaction of tertiary phosphines with azides

The Staudinger reaction of the N-substituted o-azidobenzamide 1 with triphenylphosphine or diphenylmethylphosphine allows the isolation of the intermediate phosphazides as crystalline solids, which have been characterized by spectroscopic methods. These compounds react in aza Wittig type fashion with isocyanates to give unexpectedly the corresponding 1,2,3- benzotriazinone derivative. Trapping of a Z-phosphazide by intramolecular aza Wittig reaction is reported for the first time. (C) 2000 Elsevier Science Ltd.