288160-50-9Relevant academic research and scientific papers
P-C bond formation: Synthesis of phosphino amino acids by palladium-catalysed cross-coupling
Kraatz, Heinz-Bernhard,Pletsch, Andreas
, p. 1617 - 1621 (2000)
(4-Diethylphosphanyl)- and (4-diphenylphosphanyl)-derivatives of D- and L-phenylalanine have been synthesised using a palladium-catalysed cross-coupling giving the desired products in very high yields and without racemisation. Copyright (C) 2000.
Palladium and platinum complexes of L-phephos: Acetyl-p-(diphenylphosphino)-L-phenylalanine methyl ester - A chiral ligand for transition metal complexation
Iyengar, Vineeth,Galka, Patrycja V.,Pletsch, Andreas,Kraatz, Heinz-Bernhard
, p. 1562 - 1567 (2002)
The crystal structure of the new phenylalanine-based phosphino amino acid L-PhePhos and its reactivity to form the Pd and Pt complexes (L-PhePhos)PdCl2 and (L-PhePhos)PtCl2 is reported. A new platinum hydride was quantitatively formed in the reaction of (L-PhePhos)PtCl2 with NaBH4.
