288264-99-3

Upstream product

• 203719-53-3 (-)-limonene oxide 
• 59121-82-3 (1R,2R,4S)-1-methyl-4-(prop-1-en-2-yl)cyclohexane-1,2-diol 

Downstream Products

• 1431302-69-0 (((1R,2S,4S)-2-bromo-4-(3-chloroprop-1-en-2-yl)-1-methylcyclohexyl)oxy)(isopropyl)dimethylsilane 
• 1431302-64-5 (((1R,2S,4S)-2-bromo-4-(3-iodoprop-1-en-2-yl)-1-methylcyclohexyl)oxy)(isopropyl)dimethylsilane 
• 1431302-70-3 (2S,5R,6S)-6-(2-((1S,3S,4R)-3-bromo-4-((isopropyldimethylsilyl)oxy)-4-methylcyclohexyl)allyl)-2-((tert-butyldimethylsilyl)oxy)-2-methyl-5-(prop-1-en-2-yl)cyclohexanone 
• 1431302-63-4 (2S,5R,6S)-6-(2-((1S,3S,4R)-3-bromo-4-hydroxy-4-methylcyclohexyl)allyl)-2-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohexanone 
• 1431536-56-9 (1S,2S,3S,4R)-3-(2-((1S,3S,4R)-3-bromo-4-hydroxy-4-methylcyclohexyl)allyl)-1-methyl-4-(prop-1-en-2-yl)cyclohexane-1,2-diol 
• 1431302-72-5 (2R,5S,6R)-6-(2-((1S,3S,4R)-3-bromo-4-methyl-4-(isopropyldimethylsilyl)oxycyclohexyl)allyl)-2-((tert-butyldimethylsilyl)oxy)-2-methyl-5-(prop-1-en-2-yl)cyclohexanone 
• 1431302-73-6 (2R,5S,6R)-6-(2-((1S,3S,4R)-3-bromo-4-hydroxy-4-methylcyclohexyl)allyl)-2-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohexanone 
• 1431536-57-0 (1R,2R,3R,4S)-3-(2-((1S,3S,4R)-3-bromo-4-hydroxy-4-methylcyclohexyl)allyl)-1-methyl-4-(prop-1-en-2-yl)cyclohexane-1,2-diol 
• 1431302-67-8 N'-((2R,5S)-2-((isopropyldimethylsilyl)oxy)-2-methyl-5-(prop-1-en-2-yl)cyclohexylidene)-4-methylbenzenesulfonohydrazide 
• 1431302-65-6 (((1R,4S)-2,2-dibromo-1-methyl-4-(prop-1-en-2-yl)cyclohexyl)oxy)(isopropyl)dimethylsilane 
• 1431302-68-9 (((1R,2S,4S)-2-bromo-1-methyl-4-(prop-1-en-2-yl)cyclohexyl)oxy)(isopropyl)dimethylsilane 
• 1431302-71-4 (2R,5S)-2-((tert-butyldimethylsilyl)oxy)-2-methyl-5-(prop-1-en-2-yl)cyclohexanone 
• 1431302-66-7 (2R,5S)-2-((isopropyldimethylsilyl)oxy)-2-methyl-5-(prop-1-en-2-yl)cyclohexanone 

Relevant academic research and scientific papers

Synthesis of the proposed structures of Prevezol C

The first enantioselective synthesis of the proposed relative structures of Prevezol C is reported in 11 linear steps from readily available materials. The unusual syn bromohydrin was installed via a multistep sequence culminating in a diastereoselective