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288301-44-0

(-)-3-[(1S)-4-oxo-1-(2-propenyl)-2-cyclohexenyl]propyl 2,2-dimethylpropanoate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 288301-44-0 Structure

  • Basic information

    1. Product Name: (-)-3-[(1S)-4-oxo-1-(2-propenyl)-2-cyclohexenyl]propyl 2,2-dimethylpropanoate
    2. Synonyms: (-)-3-[(1S)-4-oxo-1-(2-propenyl)-2-cyclohexenyl]propyl 2,2-dimethylpropanoate
    3. CAS NO:288301-44-0
    4. Molecular Formula:
    5. Molecular Weight: 278.392
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 288301-44-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (-)-3-[(1S)-4-oxo-1-(2-propenyl)-2-cyclohexenyl]propyl 2,2-dimethylpropanoate(CAS DataBase Reference)
    10. NIST Chemistry Reference: (-)-3-[(1S)-4-oxo-1-(2-propenyl)-2-cyclohexenyl]propyl 2,2-dimethylpropanoate(288301-44-0)
    11. EPA Substance Registry System: (-)-3-[(1S)-4-oxo-1-(2-propenyl)-2-cyclohexenyl]propyl 2,2-dimethylpropanoate(288301-44-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 288301-44-0(Hazardous Substances Data)

288301-44-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 288301-44-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,8,8,3,0 and 1 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 288301-44:
(8*2)+(7*8)+(6*8)+(5*3)+(4*0)+(3*1)+(2*4)+(1*4)=150
150 % 10 = 0
So 288301-44-0 is a valid CAS Registry Number.

288301-44-0Relevant articles and documents

Total synthesis of serofendic acids A and B employing tin-free homoallyl-homoallyl radical rearrangement

Toyota, Masahiro,Asano, Takeshi,Ihara, Masataka

, p. 3929 - 3932 (2005)

(Chemical Equation Presented) Total syntheses of serofendic acids A (1a) and B (1b) are described. The key strategic element of the approach involves the novel tin-free homoallyl-homoallyl radical rearrangement of 5 for the construction of bicyclo[2.2.2]o

Total Syntheses of (-)-Methyl Atis-16-en-19-oate, (-)-Methyl Kaur-16-en-19-oate, and (-)-Methyl Trachyloban-19-oate by a Combination of Palladium-Catalyzed Cycloalkenylation and Homoallyl-Homoallyl Radical Rearrangement

Toyota, Masahiro,Wada, Toshihiro,Ihara, Masataka

, p. 4565 - 4570 (2007/10/03)

Asymmetric total syntheses of (-)-methyl atis-16-en-19-oate (1c), (-)-methyl kaur-16-en-19-oate (2c), and (-)-methyl trachyloban-19-oate (3c) have been achieved by employing a hybrid strategy of palladium-catalyzed cycloalkenylation and homoallyl-homoallyl radical rearrangement. The common synthetic intermediate 5 was prepared from 2-allylcyclohexanone (4) with 98% ee using d'Angelo's asymmetric Michael addition. A series of functional group modifications in 5 via palladium-catalyzed cycloalkenylation led to (+)-14, which had already been prepared by us as racemate. (-)-Methyl atis-16-ene-19-oate (1c) was generated via homoallyl-homoallyl radical rearrangement. On the other hand, Wolff-Kishner reduction of 18 followed by esterification yielded (-)-methyl kaur-16-en-19-oate (2c) together with (-)-methyl trachyloban-19-oate (3c).

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