288321-69-7

Basic information

• Product Name: [(1,3-dioxo-indan-2-yl)-thiophen-2-yl-methyl]-phosphonic acid dimethyl ester
• Synonyms: [(1,3-dioxo-indan-2-yl)-thiophen-2-yl-methyl]-phosphonic acid dimethyl ester
• CAS NO: 288321-69-7
• Molecular Weight: 350.332
• Mol File: 288321-69-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(1,3-dioxo-indan-2-yl)-thiophen-2-yl-methyl]-phosphonic acid dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(1,3-dioxo-indan-2-yl)-thiophen-2-yl-methyl]-phosphonic acid dimethyl ester(288321-69-7)
• EPA Substance Registry System: [(1,3-dioxo-indan-2-yl)-thiophen-2-yl-methyl]-phosphonic acid dimethyl ester(288321-69-7)

Safety Data

• Hazardous Substances Data: 288321-69-7(Hazardous Substances Data)

Upstream product

• 96-36-6 methyl phosphite 
• 24760-36-9 2-(thiophen-2-ylmethylene)indan-1,3-dione 

Relevant articles and documents

Organophosphorus chemistry, 331 on the reaction of tervalent phosphorus nucleophiles with 2-furfurylidene-, and 2-thienylidene-1,3-indandiones

2-Furfurylidene-. (1a) and 2-thienylidene-1,3-indandione (1b) produce the respective 1:1 adducts (8 a-f) upon reaction with the appropriate dialkyl phosphite (3 a-c). The reaction of 1a,b with trialkyl phosphite (2a-c) yield a mixture of the corresponding phosphonates (7a-d) (major) and (8a-d) (minor). Triphenylphosphine (2d) and hexamethylphosphorustriamide (2e) also reacted with 1a,b. The produced betaines (10a-c) were alkylated with methyl iodide to yield the respective phosphonium iodides (11a-d). Possible reaction mechanisms were discussed. Compatible elemental and spectroscopic results were gained for the new products.