288622-62-8Relevant articles and documents
Synthesis of 4-octuloses, VI([≠]) - 4-Octulose derivatives, prepared from 1-sorbose, as key intermediates in the stereoselective synthesis of C- glycoside and polyhydroxyindolizidine analogues
Izquierdo, Isidoro,Plaza, Maria T.,Robles, Rafael,Mota, Antonio J.
, p. 2071 - 2078 (2007/10/03)
Reactions of 1 and 12 with p-toluenesulfonyl chloride in pyridine gave the corresponding 1-O-p-toluenesulfonyl derivatives 2 and 13 in yields of 91% and 60%, respectively. Compound 12 was also transformed into 14 by treatment with I2/Ph3/