28918-41-4Relevant academic research and scientific papers
Rearrangement-cleavage of ammonium salts containing a 3-methyl-2- naphthylmethyl group
Oganesyan,Grigoryan,Babayan,Kocharyan
, p. 951 - 956 (2003)
The example of the rearrangement-cleavage under the action of 25% aqueous potassium hydroxide at 90-92°C of ammonium salts containing both 3-methyl-2-naphthylmethyl and 2-bromoethyl, allyl, methallyl, 2-bromoallyl, 3-phenylallyl, 2-propynyl, or 3-phenylphenyl-2-propynyl groups was used to show that the reaction always involves the aromatic ring of the 3-methyl-2- naphthylmethyl group. Along with rearrangement-cleavage, nucleophilic substitution of the 2-naphthylmethyl group takes place.
