289472-07-7

Upstream product

• 78916-50-4 1,3-dimethoxy-5-(2-phenylethyl)benzene 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 289472-29-3 2-[(Z)-3-Methyl-4-(tetrahydro-pyran-2-yloxy)-but-2-enyl]-5-phenethyl-3-(tetrahydro-pyran-2-yloxy)-phenol 
• 289472-19-1 tert-butyl-{3-methoxy-2-[3-methyl-4-(tetrahydro-pyran-2-yloxy)-but-2-enyl]-5-phenethyl-phenoxy}-dimethyl-silane 
• 289472-28-2 C₃₀H₄₀O₅ 
• 289472-27-1 2-[(Z)-4-(2,6-Bis-methoxymethoxy-4-phenethyl-phenyl)-2-methyl-but-2-enyloxy]-tetrahydro-pyran 
• 289472-20-4 2-[(Z)-4-(2-Methoxy-6-methoxymethoxy-4-phenethyl-phenyl)-2-methyl-but-2-enyloxy]-tetrahydro-pyran 
• 289472-24-8 2-Bromomethyl-1,3-bis-(tert-butyl-dimethyl-silanyloxy)-5-phenethyl-benzene 
• 289472-08-8 2-[(Z)-4-(2,6-Dimethoxy-4-phenethyl-phenyl)-2-methyl-but-2-enyloxy]-tetrahydro-pyran 
• 289472-15-7 3-Methoxy-2-[(Z)-3-methyl-4-(tetrahydro-pyran-2-yloxy)-but-2-enyl]-5-phenethyl-phenol 
• 289472-22-6 2,6-bis-(tert-butyl-dimethyl-silanyloxy)-4-phenethyl-benzaldehyde 
• 289472-17-9 (2-bromomethyl-3-methoxy-5-phenethyl-phenoxy)-tert-butyl-dimethyl-silane 
• 289472-11-3 2-((Z)-4-Hydroxy-3-methyl-but-2-enyl)-3-methoxy-5-phenethyl-phenol 
• 289472-12-4 2-((Z)-4-Hydroxy-3-methyl-but-2-enyl)-5-phenethyl-benzene-1,3-diol 
• 289472-14-6 2-Bromomethyl-1,3-dimethoxy-5-phenethyl-benzene 
• 68104-15-4 6-methoxy-3-methyl-8-(2-phenylethyl)-2,5-dihydro-1-benzoxepin 

Relevant academic research and scientific papers

A new preparation of 2,5-dihydro-1-benzoxepins using Mitsunobu cyclization, and the synthesis of natural radulanins

Mitsunobu cyclization of o-[4-hydroxy-3-methyl-2(Z)-butenyl]phenol 2a effected selective seven-membered cyclization to give 3-methyl-2,5-dihydro-1- benoxepin 1a. Using this procedure, natural radulanin A and radulanin A methyl ether were synthesized effec

Synthesis of two naturally occurring 3-methyl-2,5-dihydro-1-benzoxepin carboxylic acids

Two naturally occurring 3-methyl-2,5-dihydro-1-benzoxepin carboxylic acids, 6-hydroxy-3-methyl-8-(phenylethyl)-2,5-dihydro-1-benzoxepin-9-carboxylic acid (radulanin E) (1) and 9-hydroxy-3-methyl-2,5-dihydro-1-benzoxepin-7-carboxylic acid (2), were synthes