28969-28-0Relevant academic research and scientific papers
Synthesis, characterization and applications of organomecury(II) pyrrolidine-N-thiohydrazide complexes
Kaushik, N. K.,Sharma, Rama
, p. 1778 - 1784 (2021/06/06)
The complexes of organomercury(II) with pyrrolidine-N-thiohydrazide of the type RHg(L)Cl where[R=C6H5(phenyl), p-ClC6H4(p-chlorophenyl), p-BrC6H4(p-bromophenyl), o-, p-HOC6H4, (o-,p-hydroxyphenyl), L = pyrrolidine-N-thiohydrazide, have been synthesized and characterized by elemental analysis, IR,1H-NMR and electronic spectral analysis. Thermogravimetric and differential thermal analytical curves are used to calculate thermodynamic parameters and variations in these parameters have been correlated with complex structural parameters. All complexes were tested in vitro for their antibacterial activity against Gram-negative bacteria, namely, Escherichia coli, Zymomonas mobilis and against two pathogenic fungal strains, namely, Aspergillus niger and Cerveleria.
Microwave induced novel synthetic route to organomercurials
Kidwai, Mazaahir,Goel, Yogesh
, p. 2819 - 2824 (2008/10/09)
Organomercurials of 2-mercapto-5-methyl-1,3,4-thiadiazole and 2-mercapto-5-[4′-methyl quinolinyl-2-oxy methyl]-1,3,4-oxadiazole with aryl mercuric chloride have been synthesized under microwave irradiation in open vessels in a domestic microwave oven within a few minutes. This reaction rate was ca 100 times faster than the reaction rate in the conventional way. These Organomercurials have a 1:1 stoichiometric ratio of aryl mercury and thiadiazole or oxadiazole moiety. Copyright
