289716-59-2Relevant academic research and scientific papers
Enantioselective synthesis of α,α'-disubstituted piperidines via ruthenium-catalyzed ring rearrangement
Voigtmann, Ulrike,Blechert, Siegfried
, p. 893 - 898 (2007/10/03)
A new method for the enantioselective synthesis of α,α'-disubstituted piperidines is described. Easily available cyclopentenones 5a,b rearrange via Ru-catalyzed RCM-ROM to heterocycles. Compound 6a is converted to the indolizidine 13.
