289721-26-2Relevant articles and documents
Palladium-catalyzed cross-benzannulation of aminoenynes with diynes. Highly regioselective synthesis of polysubstituted anilines
Saito, Shinichi,Uchiyama, Naoyuki,Gevorgyan, Vladimir,Yamamoto, Yoshinori
, p. 4338 - 4341 (2000)
Polysubstituted anilines were prepared by the palladium-catalyzed cross- benzannulation of conjugated aminoenynes 1-4 with diynes 8. The reaction proceeded in a highly regioselective manner under mild conditions, and the anilines were obtained as single regioisomers. Our method complements the well-known precedures for the preparation of polysubstituted anilines which are widely used in organic synthesis.