28991-15-3

Basic information

• Product Name: (E)-ethyl 3-(4-methoxyphenoxy)acrylate
• Synonyms: (E)-ethyl 3-(4-methoxyphenoxy)acrylate
• CAS NO: 28991-15-3
• Molecular Weight: 222.241
• Mol File: 28991-15-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-ethyl 3-(4-methoxyphenoxy)acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-ethyl 3-(4-methoxyphenoxy)acrylate(28991-15-3)
• EPA Substance Registry System: (E)-ethyl 3-(4-methoxyphenoxy)acrylate(28991-15-3)

Safety Data

• Hazardous Substances Data: 28991-15-3(Hazardous Substances Data)

Upstream product

• 31930-35-5 ethyl (E)-3-bromoacrylate 
• 150-76-5 4-methoxy-phenol 
• 623-47-2 propynoic acid ethyl ester 

Relevant articles and documents

Cobalt-catalyzed intermolecular C(sp2)-O cross-coupling

Cobalt(II)-catalyzed C(sp2)-O cross-coupling between aryl/heteroaryl alcohols and vinyl/aryl halides in the presence of CuI has been achieved under ligand-free conditions. In this reaction, copper plays a significant role in transmetalation rather than being directly involved in the C-O coupling. This unique Co/Cu-dual catalyst system provides an easy access to a library of aryl-vinyl, heteroaryl-styryl, aryl-aryl, and heteroaryl-heteroaryl ethers in the absence of any ligand or additive.

Palladium-catalyzed oxidative cyclization of 3-phenoxyacrylates: An approach to construct substituted benzofurans from phenols

In this paper, a novel and applicable synthesis of benzofurans from commercially available phenols and propiolate through the direct oxidative cyclization has been developed. In the presence of Pd(OAc)2/PPh 3 and CF3COsub