29024-90-6Relevant articles and documents
D - production of glucosamine acid or its analogs, as well as catalyst composition
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Paragraph 0076; 0077; 0078, (2017/04/28)
PROBLEM TO BE SOLVED: To provide a means for simply and efficiently producing D-glucosamic acid or its analogue.SOLUTION: By using a catalyst composition including a carrier comprising hydrotalcite, magnesium oxide or calcium oxide and gold particles carried on the carrier, it becomes possible to produce D-glucosamic acid or its analogue simply and efficiently from corresponding D-glucosamine or its analogue.
Synthesis of α-amino acids from glucosamine-HCl and its derivatives by aerobic oxidation in water catalyzed by au nanoparticles on basic supports
Ohmi, Youtaro,Nishimura, Shun,Ebitani, Kohki
, p. 2259 - 2262 (2014/01/06)
The golden wonder: Various α-amino acids such as glucosaminic acid, galactosaminic acid, or N-acetyl-glucosaminic acid can be obtained from the corresponding glucosamine derivatives (amino sugars). This is achieved through an aqueous oxidation that cataly
The reaction of hyaluronic acid and its monomers, glucuronic acid and N- acetylglucosamine, with reactive oxygen species
Jahn, Michael,Baynes, John W.,Spiteller, Gerhard
, p. 228 - 234 (2007/10/03)
Synovial fluid is a ~0.15% (w/v) aqueous solution of hyaluronic acid (HA), a polysaccharide consisting of alternating units of GlcA and GlcNAc. In synovial fluid of patients suffering from rheumatoid arthritis, HA is thought to be degraded either by radicals generated by Fenton chemistry (Fe2+/H2O2) or by NaOCl generated by myeloperoxidase. We investigated the course of model reactions of these two reactants in physiological buffer with HA, and with the corresponding monomers GlcA and GlcNAc. meso-Tartaric acid, arabinuronic acid, arabinaric acid and glucaric acid were identified by GC-MS as oxidation products of glucuronic acid. When GlcNAc was oxidised, erythronic acid, arabinonic acid, 2-acetamido-2-deoxy-gluconic acid, glyceric acid, erythrose and arabinose were formed. NaOCl oxidation of HA yielded meso-tartaric acid; in addition, arabinaric acid and glucaric acid were obtained by oxidation with Fe2+/H2O2. These results indicate that oxidative degradation of HA proceeds primarily at glucuronic acid residues. meso-Tartaric acid may be a useful biomarker of hyaluronate oxidation since it is produced by both NaOCl and Fenton chemistry.