290301-52-9Relevant academic research and scientific papers
Palladium-catalyzed intramolecular coupling of vinyl halides and ketone enolates. Synthesis of bridged azabicyclic compounds
Sole, Daniel,Peidro, Emma,Bonjoch, Josep
, p. 2225 - 2227 (2000)
(equation presented) The palladium-mediated intramolecular coupling of amino-tethered vinyl halides and ketone enolates is a useful methodology for the synthesis of nitrogen heterocycles and constitutes a new synthetic entry to the 2-azabicyclo[3.3.1]nona
One-pot synthesis of polysubstituted 3-acylpyrroles by cooperative catalysis
Cui, Hai-Lei,Tanaka, Fujie
supporting information, p. 5822 - 5826 (2014/08/05)
One-pot syntheses of polysubstituted 3-acylpyrroles from readily available unsaturated ketones and N-substituted propargylated amines have been developed. An aza-Michael/alkyne carbocyclization cascade, by cooperative catalysis using pyrrolidine and a copper salt, followed by oxidation in situ gave 3-acylpyrroles, which were also transformed further to functionalized, highly substituted 3-acylpyrroles. This journal is the Partner Organisations 2014.
Palladium-catalyzed intramolecular coupling of amino-tethered vinyl halides with ketones, esters, and nitriles using potassium phenoxide as the base
Sole, Daniel,Urbaneja, Xavier,Bonjoch, Josep
, p. 1646 - 1650 (2007/10/03)
Vinyl halides undergo intramolecular coupling with amino-tethered ketones, esters, and nitriles in the presence of a palladium catalyst and potassium phenoxide as the base. This reaction constitutes a useful methodology for the synthesis of monocyclic, br
Nitrogen heterocycles by palladium-catalyzed cyclization of amino-tethered vinyl halides and ketone enolates
Sole, Daniel,Diaba, Faiza,Bonjoch, Josep
, p. 5746 - 5749 (2007/10/03)
The scope and limitations of Pd(0)-catalyzed intramolecular coupling of amino-tethered vinyl halides and ketone enolates as a methodology for the synthesis of nitrogen heterocycles have been studied. This reaction constitutes a synthetic procedure to obta
