29148-24-1Relevant academic research and scientific papers
Mesogenic, optical, and dielectric properties of 5-substituted 2-[12-(4-pentyloxyphenyl)-p-carboran-1-yl] [1,3]dioxanes
Nagamine, Takashi,Januszko, Adam,Kaszynski, Piotr,Ohta, Kiminori,Endo, Yasuyuki
, p. 3836 - 3843 (2007/10/03)
Two homologous series of carborane-containing dioxanes 1[n] and 2[n] (n = 1-10) were prepared and their mesogenic properties investigated. All compounds exhibit nematic behavior and three members of series 2[n] show an E phase. Numerical analysis of the clearing temperatures gave a limiting value T NI(∞) of 89 °C for series 2[n] and indicated conformational flexibility of the dioxane ring. Investigations of three-ring derivative 1[4] gave Δn = 0.17, S = 0.53, and Δε = +0.4 ± 0.1 at 85 °C. Extrapolation of dielectric data for dilute solutions of 1[4] in 6-CHBT gave Δε = +0.4 ± 0.25 at 24 °C. Modelling of dielectric results with the Maier-Meier equation demonstrated that conformers with a higher β angle are preferred, which is consistent with conformational selection for the most elongated conformers. The Royal Society of Chemistry 2006.
Liquid crystalline compounds, liquid crystal compositions containing the same and use thereof
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, (2008/06/13)
Liquid crystalline compounds having an optically active γ-lactone ring of the general formula (A): STR1 wherein R1 is a group selected from the class consisting of STR2 n and e are each independently 0 or 1, R3 is an alkyl group having 1 to 15 carbon atoms or an alkenyl group having 2 to 15 carbon atoms, said alkyl and alkenyl groups having each optionally one or more asymmetric carbon atoms, X and Y are each hydrogen atom, a halogen atom or a cyano group, R2 is an alkyl group having 1 to 15 carbon atoms or an alkenyl group having 2 to 15 carbon atoms, said alkyl and alkenyl groups having each optionally one or more asymmetric carbon atoms, and * means an asymmetric carbon atom, a liquid crystal composition Containing the same and an element for opto-electronics devices comprising the liquid crystal composition.
Liquid crystalline compounds and process for production thereof
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, (2008/06/13)
Liquid crystalline compounds having an optically active γ-lactone ring of the formula: STR1 wherein R1 is a group selected from the group consisting of STR2 n and e are each independently 0 or 1; R3 is an alkyl group having 1 to 15 carbon atoms; R2 is a group of the formula: --(CO)m --R4 ; m is 0 or 1; R4 is hydrogen atom or an alkyl having 1 to 15 carbon atoms; and the symbol * is an asymmetric carbon atom, and an intermediate thereof, and process for the production of the same.
