29164-07-6Relevant academic research and scientific papers
The reductive dimerization of some 1,3-dienes and of 1,3,5-cycloheptatriene in the presence of trimethylchlorosilane: a DFT investigation
Aouf, Chahinez,El Abed, Douniazad,Giorgi, Michel,Santelli, Maurice
experimental part, p. 5563 - 5570 (2009/12/04)
Treatment of 1,3-dienes and 1,3,5-cycloheptatriene by chlorotrimethylsilane in the presence of wire of lithium led mainly to reductive dimerization with formation of bis(allylsilane) derivatives. Bis-silyl compounds obtained: from 1,3-butadiene, 1,8-bis(t
Ti-catalyzed reactions of 4,4′-bis(trimethylsilyl)bicyclohexyl-2,2′-diene with various electrophiles
Aouf, Chahinez,Abed, Douniazad El,Giorgi, Michel,Santelli, Maurice
, p. 4630 - 4632 (2008/09/21)
Reductive disilylation (Li + Me3SiCl - THF) of 1,3-cyclohexadiene led to 4,4′-bis(trimethylsilyl)bicyclohexyl-2,2′-diene (1). In the presence of TiCl4 in dichloromethane, 1 reacted with some acyl chlorides, anhydrides, and aldehydes
