292066-65-0

Upstream product

• 220441-82-7 (S)-(4-bromophenyl)(phenyl)methanamine 
• 98-80-6 phenylboronic acid 
• 1190207-24-9 (-)-(S)-N-[biphenyl-4-yl(phenyl)methyl]-P,P-diphenylphosphinic amide 

Downstream Products

• 292066-68-3 (S)-(-)-α-(4-biphenylyl)-N-(2,2-dimethoxyethyl)benzylamine 
• 91487-86-4 (S)-(+)-1-[α-(4-biphenylyl)benzyl]-1H-imidazole 
• 292066-70-7 (S)-(+)-N-[α-(4-biphenylyl)benzyl]-N-(2,2-dimethoxyethyl)formamide 
• 1190207-51-2 (R)-N-((S)-biphenyl-4-yl(phenyl)methyl)-3,3,3-trifluoro-2-methoxy-2-phenylpropanamide 

Relevant academic research and scientific papers

Steric tuning of the amidomonophosphane-rhodium(l) catalyst in asymmetric addition of arylboroxines to n-phosphinoyl aldimines

Highly enantioselective rhodium-catalyzed addition of arylboroxlnes to N-phosphinoylaldimines was realized by the steric tuning of a dlphenylphosphorus moiety to a di(o-tolyl)phosphorus moiety of a chiral amidomonophosphane. The presence of MS 4 A in a 5:1 solvent mixture of dioxane-propanol was essential to afford the corresponding dlarylmethylamines In high yield.

Practical syntheses of enantiomerically pure N-acetylbenzhydrylamines

Two practical routes for the synthesis of benzhydrylamine derivatives in enantiomerically pure form have been developed. N-Acetylbenzhydrylamines can be synthesised in few steps and good yields starting from 1-aryl-1-propargylamines. The key steps are rep