292159-44-5Relevant academic research and scientific papers
Facile synthesis of amino acid bicyclo[2.2.1]heptyl alcohol and its application for enantioselective additions of diethylzinc to aldehydes
Hanyu, Naoto,Mino, Takashi,Sakamoto, Masami,Fujita, Tsutomu
, p. 4587 - 4590 (2000)
Enatioselective additions of diethylzinc to aldehydes were demonstrated, and good to moderate enantioselectivities (54 to 95% enantiomeric excess) were obtained. The ligand 4 was prepared from camphor and acetic acid in a facile process of four steps, and
Enantioselective addition of diethylzinc to aldehydes catalyzed by optically active 1,4-aminoalcohols
Hanyu, Naoto,Aoki, Tasuku,Mino, Takashi,Sakamoto, Masami,Fujita, Tsutomu
, p. 2971 - 2979 (2007/10/03)
Enantioselective addition reactions of diethylzinc to aldehydes were performed by catalytic reactions with chiral 1,4-aminoalcohols. Optically active 1,4-aminoalcohols were synthesized from (+)-camphor and (-)-fenchone through four steps involving iodine-
