292163-77-0

Basic information

• Product Name: rac-3-(1-allyloxphenylmethyl)penta-1,4-dien-3-ol
• Synonyms: rac-3-(1-allyloxphenylmethyl)penta-1,4-dien-3-ol
• CAS NO: 292163-77-0
• Molecular Weight: 230.307
• Mol File: 292163-77-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: rac-3-(1-allyloxphenylmethyl)penta-1,4-dien-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: rac-3-(1-allyloxphenylmethyl)penta-1,4-dien-3-ol(292163-77-0)
• EPA Substance Registry System: rac-3-(1-allyloxphenylmethyl)penta-1,4-dien-3-ol(292163-77-0)

Safety Data

• Hazardous Substances Data: 292163-77-0(Hazardous Substances Data)

Upstream product

• 3536-96-7 vinylmagnesium chloride 
• 114209-14-2 (1-allyloxy-1-methoxymethyl-but-3-enyl)-benzene 
• 1469-70-1 allyl ethyl carbonate 
• 4358-87-6 (RS)-methyl mandelate 

Downstream Products

• 292163-80-5 rac-(1-allyloxy-2-phenylmetyloxy-2-vinylbut-3-enyl)benzene 
• 292163-84-9 rac-(1,2-bis-allyloxy-2-vinylbut-3-enyl)benzene 
• 853013-96-4 3-ethyl-2-phenyl-3,6-dihydro-2H-pyran-3-ol 
• 697300-66-6 3-ethyl-2-phenyl-3,4-dihydro-2H-pyran-3-ol 
• 697300-66-6 3-ethyl-2-phenyl-3,4-dihydro-2H-pyran-3-ol 
• 292163-82-7 rac-[1-(1-allyloxy-1-phenylmetyl)-1-vinylallyloxy]-tert-butyldimethylsilane 
• 697300-66-6 3-ethyl-2-phenyl-3,4-dihydro-2H-pyran-3-ol 

Relevant articles and documents

Palladium-catalyzed O-allylation of α-hydroxy carbonyl compounds

α-Hydroxy carbonyl compounds undergo smooth O-allylation using allylic carbonates and Pd(0) catalysts. This method has significant advantages over other O-allylation methods as it provides a solution to several problems previously observed for this synthe

Diastereoselective Ring-Closing Metathesis in the Synthesis of Dihydropyrans

An investigation into the factors influencing the diastereochemical outcome of the ring-closing metathesis based synthesis of dihydropyrans is presented in this paper. Divinyl carbinols derived from α-hydroxy carboxylic acid esters are elaborated to trienes with two diastereotopic vinyl moieties. Depending on the steric demand of the oxo substituent of the divinyl carbinol moiety (either unprotected OH, TBDMS, or benzyl ether) different diastereomers are preferrably formed upon ring-closing metathesis. An extension to diastereoselective double ring-closing metathesis in the formation of spirocycles has also been investigated.