292164-60-4

Basic information

• Product Name: 5,10-bis(pentafluorophenyl)tripyrrane
• Synonyms: 5,10-bis(pentafluorophenyl)tripyrrane
• CAS NO: 292164-60-4
• Molecular Weight: 557.393
• Mol File: 292164-60-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 5,10-bis(pentafluorophenyl)tripyrrane(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10-bis(pentafluorophenyl)tripyrrane(292164-60-4)
• EPA Substance Registry System: 5,10-bis(pentafluorophenyl)tripyrrane(292164-60-4)

Safety Data

• Hazardous Substances Data: 292164-60-4(Hazardous Substances Data)

Upstream product

• 109-97-7 pyrrole 
• 653-37-2 perfluorobenzaldehyde 

Downstream Products

• 1404219-63-1 5,20-bis(9-anthryl)-10,15,25,30-tetrakis(pentafluorophenyl) [26]hexaphyrin (1.1.1.1.1.1) 
• 1404219-65-3 5,20-bis[1,8-bis(2,4,6-trimethylphenoxy)anthryl]-10,15,25,30-tetrakis(pentafluorophenyl)[26]hexaphyrin(1.1.1.1.1.1) 

Relevant articles and documents

Synthesis method of cyclic tripyrrole compound with intramolecular orthogonal structure

The invention discloses a synthesis and purification method of a rigid cyclic tripyrrole compound with an intramolecular orthogonal structure. The method is based on a chain tripyrrole compound, and through a universal synthesis method, a four-membered ring compound with two orthogonal planes in a molecule is obtained. The preparation method comprises the following steps of starting from a pentafluorophenyl tripyrrole compound, carrying out bromination and oxidation reactions to obtain a bromine-terminated substituted conjugated tripyrrole compound, and then reacting the bromine-terminated substituted conjugated tripyrrole compound with a hydroquinone compound in an organic solvent to obtain a target product. Various substitution groups can be introduced into the hydroquinone compound, and huge scientific research potential can be shown in the aspects of photophysical property exploration, intermolecular interaction and the like. And more explorability and possibility can be brought to an oligomerization pyrrole compound system. The method has the characteristics of mild conditions, good conversion rate, high selectivity, flexible substituted group introduction and the like.

Control of oligomerization and oxidation steps in the synthesis of tris(pentafluorophenyl)corrole

The mechanistic features of oligomerization and oxidative cyclization steps in the synthesis of tris(pentafluorophenyl)corrole (1) have been thoroughly studied. Separation of the intermediates by preparative HPLC and analysis by NMR spectroscopy and high

Optimizing the synthesis of 5,10-disubstituted tripyrromethanes

Condensation of aldehydes with pyrrole in the presence of acid catalyst gave the mixture of dipyrromethanes and tripyrromethanes. The major product was switched from dipyrromethanes to tripyrromethanes according to the sequence of adding the reactants and