2924-34-7Relevant academic research and scientific papers
Glycosyl fluorides from n-pentenyl-related glycosyl donors-application to glycosylation strategies
Fraser-Reid, Bert,Lopez, J. Cristobal,Bernal-Albert, Paloma,Gomez, Ana M.,Uriel, Clara,Ventura, Juan
, p. 51 - 65 (2013/03/28)
n-Pentenyl glycosides (NPGs) and n-pentenyl orthoesters (NPOEs) have been transformed into glycosyl fluorides by a variety of methods. In the case of NPGs, Barluenga's reagent, bis(pyridinium)iodonium(I)tetrafluoroborate (IPy 2BF4),
Reaction of 1,2-orthoesters with HF-pyridine: A method for the preparation of partly unprotected glycosyl fluorides and their use in saccharide synthesis
Cristobal Lopez,Ventura, Juan,Uriel, Clara,Gomez, Ana M.,Fraser-Reld, Bert
supporting information; experimental part, p. 4128 - 4131 (2009/12/30)
Glycosyl fluorides can be prepared In an efficient manner by treatment of pyranose- or furanose-derlved 1,2-orthoesters, with hydrogen fluoride pyridine (HF-py). The method Is compatible with the presence of a variety of protecting groups, including fert-
THE SYNTHESIS OF GLYCOSYL FLUORIDES USING PYRIDINIUM POLY(HYDROGEN FLUORIDE)
Szarek, Walter A.,Grynkiewicz, Grzegorz,Doboszewski, Bogdan,Hay, George W.
, p. 1751 - 1754 (2007/10/02)
Partially protected monosaccharides, having the anomeric hydroxyl group underivatized, react with poly(hydrogen fluoride) to yield the corresponding glycosyl fluorides.
